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[Bis(pyridin-2-yl) selenide-κ(2) N,N′]tetra­chloridotin(IV)

The title compound, [SnCl(4)(C(10)H(8)N(2)Se)], was obtained by the reaction of 2,2′-dipyridyl diselenide with tin tetra­chloride. The Sn(IV) ion is coordinated by two N atoms [Sn—N = 2.266 (2) and 2.274 (2) Å] from the bis­(2-pyrid­yl)selenide ligand and four chloride anions [Sn—Cl = 2.3717 (6)–2.3...

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Autores principales: Mammadova, Gunay Z., Matsulevich, Zhanna V., Osmanov, Vladimir K., Borisov, Alexander V., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393232/
https://www.ncbi.nlm.nih.gov/pubmed/22807800
http://dx.doi.org/10.1107/S160053681202586X
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author Mammadova, Gunay Z.
Matsulevich, Zhanna V.
Osmanov, Vladimir K.
Borisov, Alexander V.
Khrustalev, Victor N.
author_facet Mammadova, Gunay Z.
Matsulevich, Zhanna V.
Osmanov, Vladimir K.
Borisov, Alexander V.
Khrustalev, Victor N.
author_sort Mammadova, Gunay Z.
collection PubMed
description The title compound, [SnCl(4)(C(10)H(8)N(2)Se)], was obtained by the reaction of 2,2′-dipyridyl diselenide with tin tetra­chloride. The Sn(IV) ion is coordinated by two N atoms [Sn—N = 2.266 (2) and 2.274 (2) Å] from the bis­(2-pyrid­yl)selenide ligand and four chloride anions [Sn—Cl = 2.3717 (6)–2.3939 (6) Å] in a distorted octa­hedral geometry. The central six-membered chelate ring has a boat conformation with the Se and Sn atoms deviating by 0.692 (3) and 0.855 (3) Å, respectively, from the mean plane through the remaining four ring atoms. The pyridine rings are inclined to each other by a dihedral angle of 49.62 (8)°. The crystal packing exhibits short inter­molecular Se⋯Cl contacts [3.5417 (7) and 3.5648 (7) Å], weak C—H⋯Cl hydrogen bonds and π–π stacking inter­actions between the pyridine rings with a centroid–centroid distance of 3.683 (3) Å.
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spelling pubmed-33932322012-07-17 [Bis(pyridin-2-yl) selenide-κ(2) N,N′]tetra­chloridotin(IV) Mammadova, Gunay Z. Matsulevich, Zhanna V. Osmanov, Vladimir K. Borisov, Alexander V. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [SnCl(4)(C(10)H(8)N(2)Se)], was obtained by the reaction of 2,2′-dipyridyl diselenide with tin tetra­chloride. The Sn(IV) ion is coordinated by two N atoms [Sn—N = 2.266 (2) and 2.274 (2) Å] from the bis­(2-pyrid­yl)selenide ligand and four chloride anions [Sn—Cl = 2.3717 (6)–2.3939 (6) Å] in a distorted octa­hedral geometry. The central six-membered chelate ring has a boat conformation with the Se and Sn atoms deviating by 0.692 (3) and 0.855 (3) Å, respectively, from the mean plane through the remaining four ring atoms. The pyridine rings are inclined to each other by a dihedral angle of 49.62 (8)°. The crystal packing exhibits short inter­molecular Se⋯Cl contacts [3.5417 (7) and 3.5648 (7) Å], weak C—H⋯Cl hydrogen bonds and π–π stacking inter­actions between the pyridine rings with a centroid–centroid distance of 3.683 (3) Å. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393232/ /pubmed/22807800 http://dx.doi.org/10.1107/S160053681202586X Text en © Mammadova et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mammadova, Gunay Z.
Matsulevich, Zhanna V.
Osmanov, Vladimir K.
Borisov, Alexander V.
Khrustalev, Victor N.
[Bis(pyridin-2-yl) selenide-κ(2) N,N′]tetra­chloridotin(IV)
title [Bis(pyridin-2-yl) selenide-κ(2) N,N′]tetra­chloridotin(IV)
title_full [Bis(pyridin-2-yl) selenide-κ(2) N,N′]tetra­chloridotin(IV)
title_fullStr [Bis(pyridin-2-yl) selenide-κ(2) N,N′]tetra­chloridotin(IV)
title_full_unstemmed [Bis(pyridin-2-yl) selenide-κ(2) N,N′]tetra­chloridotin(IV)
title_short [Bis(pyridin-2-yl) selenide-κ(2) N,N′]tetra­chloridotin(IV)
title_sort [bis(pyridin-2-yl) selenide-κ(2) n,n′]tetra­chloridotin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393232/
https://www.ncbi.nlm.nih.gov/pubmed/22807800
http://dx.doi.org/10.1107/S160053681202586X
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