[1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]dichloridopalladium(II) dimethyl sulfoxide monosolvate

In the title compound, [PdCl(2)(C(26)H(24)P(2))]·C(2)H(6)OS, the Pd(II) atom adopts a distorted cis-PdCl(2)P(2) square-planar coordination geometry. The five-membered chelate ring adopts an envelope conformation with a methyl­ene C atom in the flap position. The S and C atoms of the dimethyl sulfoxi...

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Autores principales: Warad, Ismail, Aldwayyan, Abdullah S., Al-Jekhedab, Fahad M., Choudhary, M. Iqbal, Yousuf, Sammer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393233/
https://www.ncbi.nlm.nih.gov/pubmed/22807801
http://dx.doi.org/10.1107/S1600536812028310
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author Warad, Ismail
Aldwayyan, Abdullah S.
Al-Jekhedab, Fahad M.
Choudhary, M. Iqbal
Yousuf, Sammer
author_facet Warad, Ismail
Aldwayyan, Abdullah S.
Al-Jekhedab, Fahad M.
Choudhary, M. Iqbal
Yousuf, Sammer
author_sort Warad, Ismail
collection PubMed
description In the title compound, [PdCl(2)(C(26)H(24)P(2))]·C(2)H(6)OS, the Pd(II) atom adopts a distorted cis-PdCl(2)P(2) square-planar coordination geometry. The five-membered chelate ring adopts an envelope conformation with a methyl­ene C atom in the flap position. The S and C atoms of the dimethyl sulfoxide (DMSO) solvent mol­ecule are disordered over two sets of sites in a 0.8976 (18):0.1024 (18) ratio. The DMSO O atom accepts three C—H⋯O hydrogen bonds from an adjacent complex mol­ecule.
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spelling pubmed-33932332012-07-17 [1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]dichloridopalladium(II) dimethyl sulfoxide monosolvate Warad, Ismail Aldwayyan, Abdullah S. Al-Jekhedab, Fahad M. Choudhary, M. Iqbal Yousuf, Sammer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(26)H(24)P(2))]·C(2)H(6)OS, the Pd(II) atom adopts a distorted cis-PdCl(2)P(2) square-planar coordination geometry. The five-membered chelate ring adopts an envelope conformation with a methyl­ene C atom in the flap position. The S and C atoms of the dimethyl sulfoxide (DMSO) solvent mol­ecule are disordered over two sets of sites in a 0.8976 (18):0.1024 (18) ratio. The DMSO O atom accepts three C—H⋯O hydrogen bonds from an adjacent complex mol­ecule. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393233/ /pubmed/22807801 http://dx.doi.org/10.1107/S1600536812028310 Text en © Warad et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Warad, Ismail
Aldwayyan, Abdullah S.
Al-Jekhedab, Fahad M.
Choudhary, M. Iqbal
Yousuf, Sammer
[1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]dichloridopalladium(II) dimethyl sulfoxide monosolvate
title [1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]dichloridopalladium(II) dimethyl sulfoxide monosolvate
title_full [1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]dichloridopalladium(II) dimethyl sulfoxide monosolvate
title_fullStr [1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]dichloridopalladium(II) dimethyl sulfoxide monosolvate
title_full_unstemmed [1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]dichloridopalladium(II) dimethyl sulfoxide monosolvate
title_short [1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]dichloridopalladium(II) dimethyl sulfoxide monosolvate
title_sort [1,2-bis(diphenyl­phosphan­yl)ethane-κ(2) p,p′]dichloridopalladium(ii) dimethyl sulfoxide monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393233/
https://www.ncbi.nlm.nih.gov/pubmed/22807801
http://dx.doi.org/10.1107/S1600536812028310
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