catena-Poly[1,2,2-trimethyl­cyclo­pentane-1,3-diammonium [aluminate(III)-μ-(hydrogen phosphato)-μ-phosphato]]

In the title compound, {(C(8)H(20)N(2))[Al(HPO(4))(PO(4))]}(n), the Al(III) atom is coordinated by four O atoms from two HPO(4) (2−) and two PO(4) (3−) groups in a distorted tetra­hedral geometry. Each AlO(4) unit shares four O atoms with four adjacent PO(4) units, leading to an anionic chain along...

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Detalles Bibliográficos
Autor principal: Liang, Li-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393234/
https://www.ncbi.nlm.nih.gov/pubmed/22807802
http://dx.doi.org/10.1107/S1600536812028826
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author Liang, Li-Li
author_facet Liang, Li-Li
author_sort Liang, Li-Li
collection PubMed
description In the title compound, {(C(8)H(20)N(2))[Al(HPO(4))(PO(4))]}(n), the Al(III) atom is coordinated by four O atoms from two HPO(4) (2−) and two PO(4) (3−) groups in a distorted tetra­hedral geometry. Each AlO(4) unit shares four O atoms with four adjacent PO(4) units, leading to an anionic chain along [100]. The negative charge of the chain is compensated by doubly protonated camphoric amine cations. N—H⋯O hydrogen bonds connect the cations and the anionic chains. O—H⋯O hydrogen bonds are present in the chain.
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spelling pubmed-33932342012-07-17 catena-Poly[1,2,2-trimethyl­cyclo­pentane-1,3-diammonium [aluminate(III)-μ-(hydrogen phosphato)-μ-phosphato]] Liang, Li-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {(C(8)H(20)N(2))[Al(HPO(4))(PO(4))]}(n), the Al(III) atom is coordinated by four O atoms from two HPO(4) (2−) and two PO(4) (3−) groups in a distorted tetra­hedral geometry. Each AlO(4) unit shares four O atoms with four adjacent PO(4) units, leading to an anionic chain along [100]. The negative charge of the chain is compensated by doubly protonated camphoric amine cations. N—H⋯O hydrogen bonds connect the cations and the anionic chains. O—H⋯O hydrogen bonds are present in the chain. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393234/ /pubmed/22807802 http://dx.doi.org/10.1107/S1600536812028826 Text en © Li-Li Liang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liang, Li-Li
catena-Poly[1,2,2-trimethyl­cyclo­pentane-1,3-diammonium [aluminate(III)-μ-(hydrogen phosphato)-μ-phosphato]]
title catena-Poly[1,2,2-trimethyl­cyclo­pentane-1,3-diammonium [aluminate(III)-μ-(hydrogen phosphato)-μ-phosphato]]
title_full catena-Poly[1,2,2-trimethyl­cyclo­pentane-1,3-diammonium [aluminate(III)-μ-(hydrogen phosphato)-μ-phosphato]]
title_fullStr catena-Poly[1,2,2-trimethyl­cyclo­pentane-1,3-diammonium [aluminate(III)-μ-(hydrogen phosphato)-μ-phosphato]]
title_full_unstemmed catena-Poly[1,2,2-trimethyl­cyclo­pentane-1,3-diammonium [aluminate(III)-μ-(hydrogen phosphato)-μ-phosphato]]
title_short catena-Poly[1,2,2-trimethyl­cyclo­pentane-1,3-diammonium [aluminate(III)-μ-(hydrogen phosphato)-μ-phosphato]]
title_sort catena-poly[1,2,2-trimethyl­cyclo­pentane-1,3-diammonium [aluminate(iii)-μ-(hydrogen phosphato)-μ-phosphato]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393234/
https://www.ncbi.nlm.nih.gov/pubmed/22807802
http://dx.doi.org/10.1107/S1600536812028826
work_keys_str_mv AT lianglili catenapoly122trimethylcyclopentane13diammoniumaluminateiiimhydrogenphosphatomphosphato

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