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catena-Poly[[gallium(III)-bis[μ-D/l-tartrato(2−)]-gallium(III)-di-μ-hydroxido] dihydrate]
In the title compound, {[Ga(2)(C(4)H(4)O(6))(2)(OH)(2)]·2H(2)O}(n), the Ga(III) atom is located on a twofold rotation axis and is six-coordinated by two O atoms from bridging hydroxide groups and four O atoms from two symmetry-related tartrate units in a slightly distorted octahedral environment. E...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393236/ https://www.ncbi.nlm.nih.gov/pubmed/22807804 http://dx.doi.org/10.1107/S1600536812028188 |
Sumario: | In the title compound, {[Ga(2)(C(4)H(4)O(6))(2)(OH)(2)]·2H(2)O}(n), the Ga(III) atom is located on a twofold rotation axis and is six-coordinated by two O atoms from bridging hydroxide groups and four O atoms from two symmetry-related tartrate units in a slightly distorted octahedral environment. Each tartrate unit binds to two Ga(III) atoms as a bis-chelating bridging ligand by two pairs of hydroxide groups and an O atom of a carboxylate group. The Ga(III) atoms are linked by two bridging hydroxide groups located on mirror planes. In this way a chain along the c axis is formed. Free water molecules on mirror planes are located between the chains and hold them together through hydrogen-bonding interactions, with O⋯O distances in the range 2.509 (3)–3.179 (5) Å. |
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