catena-Poly[[gallium(III)-bis­[μ-D/l-tartrato(2−)]-gallium(III)-di-μ-hydroxido] dihydrate]

In the title compound, {[Ga(2)(C(4)H(4)O(6))(2)(OH)(2)]·2H(2)O}(n), the Ga(III) atom is located on a twofold rotation axis and is six-coordinated by two O atoms from bridging hydroxide groups and four O atoms from two symmetry-related tartrate units in a slightly distorted octa­hedral environment. E...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Xiaojing, Tian, Ruijing, Zhang, Cailing, Zhi, Xia, Pan, Qinhe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393236/
https://www.ncbi.nlm.nih.gov/pubmed/22807804
http://dx.doi.org/10.1107/S1600536812028188
_version_ 1782237702520832000
author Liu, Xiaojing
Tian, Ruijing
Zhang, Cailing
Zhi, Xia
Pan, Qinhe
author_facet Liu, Xiaojing
Tian, Ruijing
Zhang, Cailing
Zhi, Xia
Pan, Qinhe
author_sort Liu, Xiaojing
collection PubMed
description In the title compound, {[Ga(2)(C(4)H(4)O(6))(2)(OH)(2)]·2H(2)O}(n), the Ga(III) atom is located on a twofold rotation axis and is six-coordinated by two O atoms from bridging hydroxide groups and four O atoms from two symmetry-related tartrate units in a slightly distorted octa­hedral environment. Each tartrate unit binds to two Ga(III) atoms as a bis-chelating bridging ligand by two pairs of hydroxide groups and an O atom of a carboxyl­ate group. The Ga(III) atoms are linked by two bridging hydroxide groups located on mirror planes. In this way a chain along the c axis is formed. Free water mol­ecules on mirror planes are located between the chains and hold them together through hydrogen-bonding inter­actions, with O⋯O distances in the range 2.509 (3)–3.179 (5) Å.
format Online
Article
Text
id pubmed-3393236
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33932362012-07-17 catena-Poly[[gallium(III)-bis­[μ-D/l-tartrato(2−)]-gallium(III)-di-μ-hydroxido] dihydrate] Liu, Xiaojing Tian, Ruijing Zhang, Cailing Zhi, Xia Pan, Qinhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Ga(2)(C(4)H(4)O(6))(2)(OH)(2)]·2H(2)O}(n), the Ga(III) atom is located on a twofold rotation axis and is six-coordinated by two O atoms from bridging hydroxide groups and four O atoms from two symmetry-related tartrate units in a slightly distorted octa­hedral environment. Each tartrate unit binds to two Ga(III) atoms as a bis-chelating bridging ligand by two pairs of hydroxide groups and an O atom of a carboxyl­ate group. The Ga(III) atoms are linked by two bridging hydroxide groups located on mirror planes. In this way a chain along the c axis is formed. Free water mol­ecules on mirror planes are located between the chains and hold them together through hydrogen-bonding inter­actions, with O⋯O distances in the range 2.509 (3)–3.179 (5) Å. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393236/ /pubmed/22807804 http://dx.doi.org/10.1107/S1600536812028188 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Xiaojing
Tian, Ruijing
Zhang, Cailing
Zhi, Xia
Pan, Qinhe
catena-Poly[[gallium(III)-bis­[μ-D/l-tartrato(2−)]-gallium(III)-di-μ-hydroxido] dihydrate]
title catena-Poly[[gallium(III)-bis­[μ-D/l-tartrato(2−)]-gallium(III)-di-μ-hydroxido] dihydrate]
title_full catena-Poly[[gallium(III)-bis­[μ-D/l-tartrato(2−)]-gallium(III)-di-μ-hydroxido] dihydrate]
title_fullStr catena-Poly[[gallium(III)-bis­[μ-D/l-tartrato(2−)]-gallium(III)-di-μ-hydroxido] dihydrate]
title_full_unstemmed catena-Poly[[gallium(III)-bis­[μ-D/l-tartrato(2−)]-gallium(III)-di-μ-hydroxido] dihydrate]
title_short catena-Poly[[gallium(III)-bis­[μ-D/l-tartrato(2−)]-gallium(III)-di-μ-hydroxido] dihydrate]
title_sort catena-poly[[gallium(iii)-bis­[μ-d/l-tartrato(2−)]-gallium(iii)-di-μ-hydroxido] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393236/
https://www.ncbi.nlm.nih.gov/pubmed/22807804
http://dx.doi.org/10.1107/S1600536812028188
work_keys_str_mv AT liuxiaojing catenapolygalliumiiibismdltartrato2galliumiiidimhydroxidodihydrate
AT tianruijing catenapolygalliumiiibismdltartrato2galliumiiidimhydroxidodihydrate
AT zhangcailing catenapolygalliumiiibismdltartrato2galliumiiidimhydroxidodihydrate
AT zhixia catenapolygalliumiiibismdltartrato2galliumiiidimhydroxidodihydrate
AT panqinhe catenapolygalliumiiibismdltartrato2galliumiiidimhydroxidodihydrate

Ejemplares similares