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Bromido({2-[2-(diphenylphosphanyl)benzylidene]hydrazin-1-ylidene}(4-methoxyanilino)methanethiolato)palladium(II) acetone monosolvate
In the title compound, [PdBr(C(27)H(23)N(3)OPS)]·C(3)H(6)O, the coordination geometry about the Pd(II) atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393237/ https://www.ncbi.nlm.nih.gov/pubmed/22807805 http://dx.doi.org/10.1107/S1600536812028760 |
Sumario: | In the title compound, [PdBr(C(27)H(23)N(3)OPS)]·C(3)H(6)O, the coordination geometry about the Pd(II) atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings attached to the P atom make dihedral angles of 69.78 (7), 87.05 (7) and 77.50 (7)° with each other. An intramolecular C—H⋯N hydrogen bond forms an S(6) ring motif. In the crystal, the complex molecules form infinite chains along the a-axis direction through C—H⋯Br interactions, and a C—H⋯O interaction links the main molecule with the acetone solvent molecule. |
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