Bromido({2-[2-(diphenyl­phosphan­yl)benzyl­idene]hydrazin-1-yl­idene}(4-meth­oxy­anilino)methane­thiol­ato)palladium(II) acetone monosolvate

In the title compound, [PdBr(C(27)H(23)N(3)OPS)]·C(3)H(6)O, the coordination geometry about the Pd(II) atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings...

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Autores principales: Mokthar, Khalisah Asilah, Shamsuddin, Mustaffa, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393237/
https://www.ncbi.nlm.nih.gov/pubmed/22807805
http://dx.doi.org/10.1107/S1600536812028760
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author Mokthar, Khalisah Asilah
Shamsuddin, Mustaffa
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Mokthar, Khalisah Asilah
Shamsuddin, Mustaffa
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Mokthar, Khalisah Asilah
collection PubMed
description In the title compound, [PdBr(C(27)H(23)N(3)OPS)]·C(3)H(6)O, the coordination geometry about the Pd(II) atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings attached to the P atom make dihedral angles of 69.78 (7), 87.05 (7) and 77.50 (7)° with each other. An intra­molecular C—H⋯N hydrogen bond forms an S(6) ring motif. In the crystal, the complex mol­ecules form infinite chains along the a-axis direction through C—H⋯Br inter­actions, and a C—H⋯O inter­action links the main mol­ecule with the acetone solvent mol­ecule.
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spelling pubmed-33932372012-07-17 Bromido({2-[2-(diphenyl­phosphan­yl)benzyl­idene]hydrazin-1-yl­idene}(4-meth­oxy­anilino)methane­thiol­ato)palladium(II) acetone monosolvate Mokthar, Khalisah Asilah Shamsuddin, Mustaffa Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdBr(C(27)H(23)N(3)OPS)]·C(3)H(6)O, the coordination geometry about the Pd(II) atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings attached to the P atom make dihedral angles of 69.78 (7), 87.05 (7) and 77.50 (7)° with each other. An intra­molecular C—H⋯N hydrogen bond forms an S(6) ring motif. In the crystal, the complex mol­ecules form infinite chains along the a-axis direction through C—H⋯Br inter­actions, and a C—H⋯O inter­action links the main mol­ecule with the acetone solvent mol­ecule. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393237/ /pubmed/22807805 http://dx.doi.org/10.1107/S1600536812028760 Text en © Mokthar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mokthar, Khalisah Asilah
Shamsuddin, Mustaffa
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
Bromido({2-[2-(diphenyl­phosphan­yl)benzyl­idene]hydrazin-1-yl­idene}(4-meth­oxy­anilino)methane­thiol­ato)palladium(II) acetone monosolvate
title Bromido({2-[2-(diphenyl­phosphan­yl)benzyl­idene]hydrazin-1-yl­idene}(4-meth­oxy­anilino)methane­thiol­ato)palladium(II) acetone monosolvate
title_full Bromido({2-[2-(diphenyl­phosphan­yl)benzyl­idene]hydrazin-1-yl­idene}(4-meth­oxy­anilino)methane­thiol­ato)palladium(II) acetone monosolvate
title_fullStr Bromido({2-[2-(diphenyl­phosphan­yl)benzyl­idene]hydrazin-1-yl­idene}(4-meth­oxy­anilino)methane­thiol­ato)palladium(II) acetone monosolvate
title_full_unstemmed Bromido({2-[2-(diphenyl­phosphan­yl)benzyl­idene]hydrazin-1-yl­idene}(4-meth­oxy­anilino)methane­thiol­ato)palladium(II) acetone monosolvate
title_short Bromido({2-[2-(diphenyl­phosphan­yl)benzyl­idene]hydrazin-1-yl­idene}(4-meth­oxy­anilino)methane­thiol­ato)palladium(II) acetone monosolvate
title_sort bromido({2-[2-(diphenyl­phosphan­yl)benzyl­idene]hydrazin-1-yl­idene}(4-meth­oxy­anilino)methane­thiol­ato)palladium(ii) acetone monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393237/
https://www.ncbi.nlm.nih.gov/pubmed/22807805
http://dx.doi.org/10.1107/S1600536812028760
work_keys_str_mv AT moktharkhalisahasilah bromido22diphenylphosphanylbenzylidenehydrazin1ylidene4methoxyanilinomethanethiolatopalladiumiiacetonemonosolvate
AT shamsuddinmustaffa bromido22diphenylphosphanylbenzylidenehydrazin1ylidene4methoxyanilinomethanethiolatopalladiumiiacetonemonosolvate
AT roslimohdmustaqim bromido22diphenylphosphanylbenzylidenehydrazin1ylidene4methoxyanilinomethanethiolatopalladiumiiacetonemonosolvate
AT funhoongkun bromido22diphenylphosphanylbenzylidenehydrazin1ylidene4methoxyanilinomethanethiolatopalladiumiiacetonemonosolvate

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