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Di-μ-azido-κ(4) N:N-bis({2-[(3-amino-2,2-dimethylpropyl)iminomethyl]-6-methoxyphenolato-1κ(3) N,N′,O (1)}copper(II))
The complete molecule of the title complex, [Cu(2)(C(13)H(19)N(2)O(2))(2)(N(3))(2)], is generated by the application of a centre of inversion. The central Cu(2)N(2) core is a rhombus as the μ(2)-azide ligands bridge in an asymmetric fashion. Each Cu(II) atom is also coordinated by a monoanionic tri...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393238/ https://www.ncbi.nlm.nih.gov/pubmed/22807806 http://dx.doi.org/10.1107/S1600536812028954 |
Sumario: | The complete molecule of the title complex, [Cu(2)(C(13)H(19)N(2)O(2))(2)(N(3))(2)], is generated by the application of a centre of inversion. The central Cu(2)N(2) core is a rhombus as the μ(2)-azide ligands bridge in an asymmetric fashion. Each Cu(II) atom is also coordinated by a monoanionic tridentate Schiff base ligand via the anticipated oxide O, imine N and amine N atoms. The resulting N(4)O coordination geometry is based on a square pyramid. No specific intermolecular interactions are noted in the crystal packing, but the amine H atoms form intramolecular N—H⋯O(oxide)/N(azide) hydrogen bonds. |
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