Di-μ-azido-κ(4) N:N-bis­({2-[(3-amino-2,2-dimethyl­prop­yl)imino­meth­yl]-6-meth­oxy­phenolato-1κ(3) N,N′,O (1)}copper(II))

The complete mol­ecule of the title complex, [Cu(2)(C(13)H(19)N(2)O(2))(2)(N(3))(2)], is generated by the application of a centre of inversion. The central Cu(2)N(2) core is a rhombus as the μ(2)-azide ligands bridge in an asymmetric fashion. Each Cu(II) atom is also coordinated by a monoanionic tri...

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Autores principales: Ghaemi, Akbar, Rayati, Saeed, Fayyazi, Kazem, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393238/
https://www.ncbi.nlm.nih.gov/pubmed/22807806
http://dx.doi.org/10.1107/S1600536812028954
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author Ghaemi, Akbar
Rayati, Saeed
Fayyazi, Kazem
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Ghaemi, Akbar
Rayati, Saeed
Fayyazi, Kazem
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Ghaemi, Akbar
collection PubMed
description The complete mol­ecule of the title complex, [Cu(2)(C(13)H(19)N(2)O(2))(2)(N(3))(2)], is generated by the application of a centre of inversion. The central Cu(2)N(2) core is a rhombus as the μ(2)-azide ligands bridge in an asymmetric fashion. Each Cu(II) atom is also coordinated by a monoanionic tridentate Schiff base ligand via the anti­cipated oxide O, imine N and amine N atoms. The resulting N(4)O coordination geometry is based on a square pyramid. No specific inter­molecular inter­actions are noted in the crystal packing, but the amine H atoms form intra­molecular N—H⋯O(oxide)/N(azide) hydrogen bonds.
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spelling pubmed-33932382012-07-17 Di-μ-azido-κ(4) N:N-bis­({2-[(3-amino-2,2-dimethyl­prop­yl)imino­meth­yl]-6-meth­oxy­phenolato-1κ(3) N,N′,O (1)}copper(II)) Ghaemi, Akbar Rayati, Saeed Fayyazi, Kazem Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete mol­ecule of the title complex, [Cu(2)(C(13)H(19)N(2)O(2))(2)(N(3))(2)], is generated by the application of a centre of inversion. The central Cu(2)N(2) core is a rhombus as the μ(2)-azide ligands bridge in an asymmetric fashion. Each Cu(II) atom is also coordinated by a monoanionic tridentate Schiff base ligand via the anti­cipated oxide O, imine N and amine N atoms. The resulting N(4)O coordination geometry is based on a square pyramid. No specific inter­molecular inter­actions are noted in the crystal packing, but the amine H atoms form intra­molecular N—H⋯O(oxide)/N(azide) hydrogen bonds. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393238/ /pubmed/22807806 http://dx.doi.org/10.1107/S1600536812028954 Text en © Ghaemi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ghaemi, Akbar
Rayati, Saeed
Fayyazi, Kazem
Ng, Seik Weng
Tiekink, Edward R. T.
Di-μ-azido-κ(4) N:N-bis­({2-[(3-amino-2,2-dimethyl­prop­yl)imino­meth­yl]-6-meth­oxy­phenolato-1κ(3) N,N′,O (1)}copper(II))
title Di-μ-azido-κ(4) N:N-bis­({2-[(3-amino-2,2-dimethyl­prop­yl)imino­meth­yl]-6-meth­oxy­phenolato-1κ(3) N,N′,O (1)}copper(II))
title_full Di-μ-azido-κ(4) N:N-bis­({2-[(3-amino-2,2-dimethyl­prop­yl)imino­meth­yl]-6-meth­oxy­phenolato-1κ(3) N,N′,O (1)}copper(II))
title_fullStr Di-μ-azido-κ(4) N:N-bis­({2-[(3-amino-2,2-dimethyl­prop­yl)imino­meth­yl]-6-meth­oxy­phenolato-1κ(3) N,N′,O (1)}copper(II))
title_full_unstemmed Di-μ-azido-κ(4) N:N-bis­({2-[(3-amino-2,2-dimethyl­prop­yl)imino­meth­yl]-6-meth­oxy­phenolato-1κ(3) N,N′,O (1)}copper(II))
title_short Di-μ-azido-κ(4) N:N-bis­({2-[(3-amino-2,2-dimethyl­prop­yl)imino­meth­yl]-6-meth­oxy­phenolato-1κ(3) N,N′,O (1)}copper(II))
title_sort di-μ-azido-κ(4) n:n-bis­({2-[(3-amino-2,2-dimethyl­prop­yl)imino­meth­yl]-6-meth­oxy­phenolato-1κ(3) n,n′,o (1)}copper(ii))
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393238/
https://www.ncbi.nlm.nih.gov/pubmed/22807806
http://dx.doi.org/10.1107/S1600536812028954
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