1-Ferrocenyl-3-(2-methyl­anilino)propan-1-one

In the ferrocene-containing Mannich base, [Fe(C(5)H(5))(C(15)H(16)NO)], the dihedral angle between the mean planes of the benzene ring and the substituted cyclo­penta­dienyl ring is 84.63 (7)°. The conformation of the title compound significantly differs from those found in corresponding m-tolyl­ami...

Descripción completa

Detalles Bibliográficos
Autores principales: Leka, Zorica, Novaković, Sladjana B., Pejović, Anka, Bogdanović, Goran A., Vukićević, Rastko D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393239/
https://www.ncbi.nlm.nih.gov/pubmed/22807807
http://dx.doi.org/10.1107/S1600536812028802
_version_ 1782237703211843584
author Leka, Zorica
Novaković, Sladjana B.
Pejović, Anka
Bogdanović, Goran A.
Vukićević, Rastko D.
author_facet Leka, Zorica
Novaković, Sladjana B.
Pejović, Anka
Bogdanović, Goran A.
Vukićević, Rastko D.
author_sort Leka, Zorica
collection PubMed
description In the ferrocene-containing Mannich base, [Fe(C(5)H(5))(C(15)H(16)NO)], the dihedral angle between the mean planes of the benzene ring and the substituted cyclo­penta­dienyl ring is 84.63 (7)°. The conformation of the title compound significantly differs from those found in corresponding m-tolyl­amino and p-tolyl­amino derivatives. In the crystal, C—H⋯O inter­actions connect the mol­ecules into chains, which further inter­act by means of C—H⋯π inter­actions. It is noteworthy that the amino H atom is shielded and is not involved in hydrogen bonding.
format Online
Article
Text
id pubmed-3393239
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33932392012-07-17 1-Ferrocenyl-3-(2-methyl­anilino)propan-1-one Leka, Zorica Novaković, Sladjana B. Pejović, Anka Bogdanović, Goran A. Vukićević, Rastko D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the ferrocene-containing Mannich base, [Fe(C(5)H(5))(C(15)H(16)NO)], the dihedral angle between the mean planes of the benzene ring and the substituted cyclo­penta­dienyl ring is 84.63 (7)°. The conformation of the title compound significantly differs from those found in corresponding m-tolyl­amino and p-tolyl­amino derivatives. In the crystal, C—H⋯O inter­actions connect the mol­ecules into chains, which further inter­act by means of C—H⋯π inter­actions. It is noteworthy that the amino H atom is shielded and is not involved in hydrogen bonding. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393239/ /pubmed/22807807 http://dx.doi.org/10.1107/S1600536812028802 Text en © Leka et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Leka, Zorica
Novaković, Sladjana B.
Pejović, Anka
Bogdanović, Goran A.
Vukićević, Rastko D.
1-Ferrocenyl-3-(2-methyl­anilino)propan-1-one
title 1-Ferrocenyl-3-(2-methyl­anilino)propan-1-one
title_full 1-Ferrocenyl-3-(2-methyl­anilino)propan-1-one
title_fullStr 1-Ferrocenyl-3-(2-methyl­anilino)propan-1-one
title_full_unstemmed 1-Ferrocenyl-3-(2-methyl­anilino)propan-1-one
title_short 1-Ferrocenyl-3-(2-methyl­anilino)propan-1-one
title_sort 1-ferrocenyl-3-(2-methyl­anilino)propan-1-one
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393239/
https://www.ncbi.nlm.nih.gov/pubmed/22807807
http://dx.doi.org/10.1107/S1600536812028802
work_keys_str_mv AT lekazorica 1ferrocenyl32methylanilinopropan1one
AT novakovicsladjanab 1ferrocenyl32methylanilinopropan1one
AT pejovicanka 1ferrocenyl32methylanilinopropan1one
AT bogdanovicgorana 1ferrocenyl32methylanilinopropan1one
AT vukicevicrastkod 1ferrocenyl32methylanilinopropan1one

Ejemplares similares