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Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2,2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II)
In the title Schiff base complex, [Ni(C(18)H(14)Cl(4)N(2)O(2))(C(3)H(7)NO)(2)], the geometry around the Ni(II) atom is distorted octahedral. It is coordinated by the N(2)O(2) donor atoms of the tetradentate Schiff base ligand and the O atoms of two dimethylformamide molecules, which are cis to o...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393240/ https://www.ncbi.nlm.nih.gov/pubmed/22807808 http://dx.doi.org/10.1107/S1600536812028681 |
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| author | Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz |
| author_facet | Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz |
| author_sort | Kargar, Hadi |
| collection | PubMed |
| description | In the title Schiff base complex, [Ni(C(18)H(14)Cl(4)N(2)O(2))(C(3)H(7)NO)(2)], the geometry around the Ni(II) atom is distorted octahedral. It is coordinated by the N(2)O(2) donor atoms of the tetradentate Schiff base ligand and the O atoms of two dimethylformamide molecules, which are cis to one another. The benzene rings are almost normal to each other [dihedral angle = 88.60 (14)°]. The various intramolecular C—H⋯O hydrogen bonds make S(5) and S(6) ring motifs. In the crystal, molecules are linked by pairs of weak C—H⋯Cl interactions, forming inversion dimers. |
| format | Online Article Text |
| id | pubmed-3393240 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33932402012-07-17 Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2,2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II) Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Schiff base complex, [Ni(C(18)H(14)Cl(4)N(2)O(2))(C(3)H(7)NO)(2)], the geometry around the Ni(II) atom is distorted octahedral. It is coordinated by the N(2)O(2) donor atoms of the tetradentate Schiff base ligand and the O atoms of two dimethylformamide molecules, which are cis to one another. The benzene rings are almost normal to each other [dihedral angle = 88.60 (14)°]. The various intramolecular C—H⋯O hydrogen bonds make S(5) and S(6) ring motifs. In the crystal, molecules are linked by pairs of weak C—H⋯Cl interactions, forming inversion dimers. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393240/ /pubmed/22807808 http://dx.doi.org/10.1107/S1600536812028681 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2,2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II) |
| title | Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2,2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_full | Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2,2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_fullStr | Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2,2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_full_unstemmed | Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2,2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_short | Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2,2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_sort | bis(dimethylformamide-κo){4,4′,6,6′-tetrachloro-2,2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ(4)
o,n,n′,o′}nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393240/ https://www.ncbi.nlm.nih.gov/pubmed/22807808 http://dx.doi.org/10.1107/S1600536812028681 |
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