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[4-Bromo-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]iodido(triphenyl­phosphane-κP)copper(I)

In the title compound, [CuI(C(12)H(9)BrN(2))(C(18)H(15)P)], the Cu(I) ion is bonded to one I atom, one triphenyl­phosphane P atom and two N atoms of the diimine ligand in a distorted tetra­hedral geometry. The Schiff base acts as a chelating ligand and coordinates to the Cu(I) atom via two N atoms....

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Autores principales: Khalaji, Aliakbar Dehno, Bahramian, Bahram, Jafari, Khadijeh, Fejfarová, Karla, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393242/
https://www.ncbi.nlm.nih.gov/pubmed/22807702
http://dx.doi.org/10.1107/S160053681202884X
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author Khalaji, Aliakbar Dehno
Bahramian, Bahram
Jafari, Khadijeh
Fejfarová, Karla
Dušek, Michal
author_facet Khalaji, Aliakbar Dehno
Bahramian, Bahram
Jafari, Khadijeh
Fejfarová, Karla
Dušek, Michal
author_sort Khalaji, Aliakbar Dehno
collection PubMed
description In the title compound, [CuI(C(12)H(9)BrN(2))(C(18)H(15)P)], the Cu(I) ion is bonded to one I atom, one triphenyl­phosphane P atom and two N atoms of the diimine ligand in a distorted tetra­hedral geometry. The Schiff base acts as a chelating ligand and coordinates to the Cu(I) atom via two N atoms. In the diimine ligand, the dihedral angle between the pyridine and bromo­phenyl rings is 19.2 (2)°. In the crystal, mol­ecules are connected by π–π stacking inter­actions between inversion-related pyridine rings [centroid–centroid distance = 3.404 (3) Å].
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spelling pubmed-33932422012-07-17 [4-Bromo-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]iodido(triphenyl­phosphane-κP)copper(I) Khalaji, Aliakbar Dehno Bahramian, Bahram Jafari, Khadijeh Fejfarová, Karla Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuI(C(12)H(9)BrN(2))(C(18)H(15)P)], the Cu(I) ion is bonded to one I atom, one triphenyl­phosphane P atom and two N atoms of the diimine ligand in a distorted tetra­hedral geometry. The Schiff base acts as a chelating ligand and coordinates to the Cu(I) atom via two N atoms. In the diimine ligand, the dihedral angle between the pyridine and bromo­phenyl rings is 19.2 (2)°. In the crystal, mol­ecules are connected by π–π stacking inter­actions between inversion-related pyridine rings [centroid–centroid distance = 3.404 (3) Å]. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393242/ /pubmed/22807702 http://dx.doi.org/10.1107/S160053681202884X Text en © Khalaji et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khalaji, Aliakbar Dehno
Bahramian, Bahram
Jafari, Khadijeh
Fejfarová, Karla
Dušek, Michal
[4-Bromo-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]iodido(triphenyl­phosphane-κP)copper(I)
title [4-Bromo-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]iodido(triphenyl­phosphane-κP)copper(I)
title_full [4-Bromo-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]iodido(triphenyl­phosphane-κP)copper(I)
title_fullStr [4-Bromo-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]iodido(triphenyl­phosphane-κP)copper(I)
title_full_unstemmed [4-Bromo-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]iodido(triphenyl­phosphane-κP)copper(I)
title_short [4-Bromo-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]iodido(triphenyl­phosphane-κP)copper(I)
title_sort [4-bromo-n-(pyridin-2-yl­methyl­idene)aniline-κ(2) n,n′]iodido(triphenyl­phosphane-κp)copper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393242/
https://www.ncbi.nlm.nih.gov/pubmed/22807702
http://dx.doi.org/10.1107/S160053681202884X
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