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[4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ(2) N,N′]iodido(triphenylphosphane-κP)copper(I)
In the title compound, [CuI(C(12)H(9)BrN(2))(C(18)H(15)P)], the Cu(I) ion is bonded to one I atom, one triphenylphosphane P atom and two N atoms of the diimine ligand in a distorted tetrahedral geometry. The Schiff base acts as a chelating ligand and coordinates to the Cu(I) atom via two N atoms....
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393242/ https://www.ncbi.nlm.nih.gov/pubmed/22807702 http://dx.doi.org/10.1107/S160053681202884X |
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author | Khalaji, Aliakbar Dehno Bahramian, Bahram Jafari, Khadijeh Fejfarová, Karla Dušek, Michal |
author_facet | Khalaji, Aliakbar Dehno Bahramian, Bahram Jafari, Khadijeh Fejfarová, Karla Dušek, Michal |
author_sort | Khalaji, Aliakbar Dehno |
collection | PubMed |
description | In the title compound, [CuI(C(12)H(9)BrN(2))(C(18)H(15)P)], the Cu(I) ion is bonded to one I atom, one triphenylphosphane P atom and two N atoms of the diimine ligand in a distorted tetrahedral geometry. The Schiff base acts as a chelating ligand and coordinates to the Cu(I) atom via two N atoms. In the diimine ligand, the dihedral angle between the pyridine and bromophenyl rings is 19.2 (2)°. In the crystal, molecules are connected by π–π stacking interactions between inversion-related pyridine rings [centroid–centroid distance = 3.404 (3) Å]. |
format | Online Article Text |
id | pubmed-3393242 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33932422012-07-17 [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ(2) N,N′]iodido(triphenylphosphane-κP)copper(I) Khalaji, Aliakbar Dehno Bahramian, Bahram Jafari, Khadijeh Fejfarová, Karla Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuI(C(12)H(9)BrN(2))(C(18)H(15)P)], the Cu(I) ion is bonded to one I atom, one triphenylphosphane P atom and two N atoms of the diimine ligand in a distorted tetrahedral geometry. The Schiff base acts as a chelating ligand and coordinates to the Cu(I) atom via two N atoms. In the diimine ligand, the dihedral angle between the pyridine and bromophenyl rings is 19.2 (2)°. In the crystal, molecules are connected by π–π stacking interactions between inversion-related pyridine rings [centroid–centroid distance = 3.404 (3) Å]. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393242/ /pubmed/22807702 http://dx.doi.org/10.1107/S160053681202884X Text en © Khalaji et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Khalaji, Aliakbar Dehno Bahramian, Bahram Jafari, Khadijeh Fejfarová, Karla Dušek, Michal [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ(2) N,N′]iodido(triphenylphosphane-κP)copper(I) |
title | [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ(2)
N,N′]iodido(triphenylphosphane-κP)copper(I) |
title_full | [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ(2)
N,N′]iodido(triphenylphosphane-κP)copper(I) |
title_fullStr | [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ(2)
N,N′]iodido(triphenylphosphane-κP)copper(I) |
title_full_unstemmed | [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ(2)
N,N′]iodido(triphenylphosphane-κP)copper(I) |
title_short | [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ(2)
N,N′]iodido(triphenylphosphane-κP)copper(I) |
title_sort | [4-bromo-n-(pyridin-2-ylmethylidene)aniline-κ(2)
n,n′]iodido(triphenylphosphane-κp)copper(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393242/ https://www.ncbi.nlm.nih.gov/pubmed/22807702 http://dx.doi.org/10.1107/S160053681202884X |
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