μ-2,2′-Bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′)-bis­[iodido(triphenyl­phosphane-κP)copper(I)] dimethyl­formamide disolvate

In the title binuclear centrosymmetric complex, [Cu(2)I(2)(C(8)H(6)N(4))(C(18)H(15)P)(2)]·2C(3)H(7)NO, the bis-bidentate 2,2′-bipyrimidine ligand bridges two copper(I) ions, each additionally bound to an iodide anion and a triphenyl­phosphane ligand in a distorted tetra­hedral N(2)IP geometry. The c...

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Detalles Bibliográficos
Autor principal: Fettouhi, Mohammed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393243/
https://www.ncbi.nlm.nih.gov/pubmed/22807703
http://dx.doi.org/10.1107/S1600536812028139
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author Fettouhi, Mohammed
author_facet Fettouhi, Mohammed
author_sort Fettouhi, Mohammed
collection PubMed
description In the title binuclear centrosymmetric complex, [Cu(2)I(2)(C(8)H(6)N(4))(C(18)H(15)P)(2)]·2C(3)H(7)NO, the bis-bidentate 2,2′-bipyrimidine ligand bridges two copper(I) ions, each additionally bound to an iodide anion and a triphenyl­phosphane ligand in a distorted tetra­hedral N(2)IP geometry. The complex mol­ecules pack in columns parallel to [100] generating cavities occupied by dimethyl­formamide solvent mol­ecules. Weak C—H⋯I hydrogen-bonding inter­actions help to stabilize the crystal packing.
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spelling pubmed-33932432012-07-17 μ-2,2′-Bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′)-bis­[iodido(triphenyl­phosphane-κP)copper(I)] dimethyl­formamide disolvate Fettouhi, Mohammed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title binuclear centrosymmetric complex, [Cu(2)I(2)(C(8)H(6)N(4))(C(18)H(15)P)(2)]·2C(3)H(7)NO, the bis-bidentate 2,2′-bipyrimidine ligand bridges two copper(I) ions, each additionally bound to an iodide anion and a triphenyl­phosphane ligand in a distorted tetra­hedral N(2)IP geometry. The complex mol­ecules pack in columns parallel to [100] generating cavities occupied by dimethyl­formamide solvent mol­ecules. Weak C—H⋯I hydrogen-bonding inter­actions help to stabilize the crystal packing. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393243/ /pubmed/22807703 http://dx.doi.org/10.1107/S1600536812028139 Text en © Mohammed Fettouhi 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fettouhi, Mohammed
μ-2,2′-Bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′)-bis­[iodido(triphenyl­phosphane-κP)copper(I)] dimethyl­formamide disolvate
title μ-2,2′-Bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′)-bis­[iodido(triphenyl­phosphane-κP)copper(I)] dimethyl­formamide disolvate
title_full μ-2,2′-Bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′)-bis­[iodido(triphenyl­phosphane-κP)copper(I)] dimethyl­formamide disolvate
title_fullStr μ-2,2′-Bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′)-bis­[iodido(triphenyl­phosphane-κP)copper(I)] dimethyl­formamide disolvate
title_full_unstemmed μ-2,2′-Bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′)-bis­[iodido(triphenyl­phosphane-κP)copper(I)] dimethyl­formamide disolvate
title_short μ-2,2′-Bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′)-bis­[iodido(triphenyl­phosphane-κP)copper(I)] dimethyl­formamide disolvate
title_sort μ-2,2′-bipyrimidine-κ(4) n (1),n (1′):n (3),n (3′)-bis­[iodido(triphenyl­phosphane-κp)copper(i)] dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393243/
https://www.ncbi.nlm.nih.gov/pubmed/22807703
http://dx.doi.org/10.1107/S1600536812028139
work_keys_str_mv AT fettouhimohammed m22bipyrimidinek4n1n1n3n3bisiodidotriphenylphosphanekpcopperidimethylformamidedisolvate

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