Dibromido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)cadmium

In the title compound, [CdBr(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal–bipyramidal geometry by two N atoms from one 4,4′-dimethyl-2,2′-bipyridine (DMBP) ligand, one O atom from a dimethyl sulfoxide (DMSO) ligand and two Br atoms. A weak intra­molecu...

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Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393245/
https://www.ncbi.nlm.nih.gov/pubmed/22807705
http://dx.doi.org/10.1107/S1600536812028553
Descripción
Sumario:In the title compound, [CdBr(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal–bipyramidal geometry by two N atoms from one 4,4′-dimethyl-2,2′-bipyridine (DMBP) ligand, one O atom from a dimethyl sulfoxide (DMSO) ligand and two Br atoms. A weak intra­molecular C—H⋯O hydrogen bond occurs between the DMBP and DMSO ligands. π–π stacking between pyridine rings [centroid–centroid distances = 3.682 (3) and 3.598 (3) Å] is observed in the crystal.

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