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Diaquabis(nitrato-κ(2) O,O′)bis(pyrazine-2-carboxamide-κN (4))cadmium–pyrazine-2-carboxamide (1/2)
In the title compound, [Cd(NO(3))(2)(C(5)H(5)N(3)O)(2)(H(2)O)(2)]·2C(5)H(5)N(3)O, the Cd(II) cation is located on a twofold rotation axis and is coordinated by two pyrazine-2-carboxamide ligands and two water molecules and chelated by two nitrate anions in a distorted square-antiprismatic geometry...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393246/ https://www.ncbi.nlm.nih.gov/pubmed/22807706 http://dx.doi.org/10.1107/S1600536812028577 |
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author | Shirvan, Sadif A. Haydari Dezfuli, Sara |
author_facet | Shirvan, Sadif A. Haydari Dezfuli, Sara |
author_sort | Shirvan, Sadif A. |
collection | PubMed |
description | In the title compound, [Cd(NO(3))(2)(C(5)H(5)N(3)O)(2)(H(2)O)(2)]·2C(5)H(5)N(3)O, the Cd(II) cation is located on a twofold rotation axis and is coordinated by two pyrazine-2-carboxamide ligands and two water molecules and chelated by two nitrate anions in a distorted square-antiprismatic geometry. Extensive intermolecular N—H⋯O, N—H⋯N, O—H⋯O and O—H⋯N hydrogen bonds, as well as weak intermolecular C—H⋯N and C—H⋯O interactions occur in the crystal. π–π stacking between between pyrazine rings of coordinating ligands and lattice molecules [centroid–centroid distance = 3.5669 (14) Å] may further stabilize the structure. |
format | Online Article Text |
id | pubmed-3393246 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33932462012-07-17 Diaquabis(nitrato-κ(2) O,O′)bis(pyrazine-2-carboxamide-κN (4))cadmium–pyrazine-2-carboxamide (1/2) Shirvan, Sadif A. Haydari Dezfuli, Sara Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(NO(3))(2)(C(5)H(5)N(3)O)(2)(H(2)O)(2)]·2C(5)H(5)N(3)O, the Cd(II) cation is located on a twofold rotation axis and is coordinated by two pyrazine-2-carboxamide ligands and two water molecules and chelated by two nitrate anions in a distorted square-antiprismatic geometry. Extensive intermolecular N—H⋯O, N—H⋯N, O—H⋯O and O—H⋯N hydrogen bonds, as well as weak intermolecular C—H⋯N and C—H⋯O interactions occur in the crystal. π–π stacking between between pyrazine rings of coordinating ligands and lattice molecules [centroid–centroid distance = 3.5669 (14) Å] may further stabilize the structure. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393246/ /pubmed/22807706 http://dx.doi.org/10.1107/S1600536812028577 Text en © Shirvan and Haydari Dezfuli 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shirvan, Sadif A. Haydari Dezfuli, Sara Diaquabis(nitrato-κ(2) O,O′)bis(pyrazine-2-carboxamide-κN (4))cadmium–pyrazine-2-carboxamide (1/2) |
title | Diaquabis(nitrato-κ(2)
O,O′)bis(pyrazine-2-carboxamide-κN
(4))cadmium–pyrazine-2-carboxamide (1/2) |
title_full | Diaquabis(nitrato-κ(2)
O,O′)bis(pyrazine-2-carboxamide-κN
(4))cadmium–pyrazine-2-carboxamide (1/2) |
title_fullStr | Diaquabis(nitrato-κ(2)
O,O′)bis(pyrazine-2-carboxamide-κN
(4))cadmium–pyrazine-2-carboxamide (1/2) |
title_full_unstemmed | Diaquabis(nitrato-κ(2)
O,O′)bis(pyrazine-2-carboxamide-κN
(4))cadmium–pyrazine-2-carboxamide (1/2) |
title_short | Diaquabis(nitrato-κ(2)
O,O′)bis(pyrazine-2-carboxamide-κN
(4))cadmium–pyrazine-2-carboxamide (1/2) |
title_sort | diaquabis(nitrato-κ(2)
o,o′)bis(pyrazine-2-carboxamide-κn
(4))cadmium–pyrazine-2-carboxamide (1/2) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393246/ https://www.ncbi.nlm.nih.gov/pubmed/22807706 http://dx.doi.org/10.1107/S1600536812028577 |
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