Cargando…

Diaqua­bis­(nitrato-κ(2) O,O′)bis­(pyrazine-2-carboxamide-κN (4))cadmium–pyrazine-2-carboxamide (1/2)

In the title compound, [Cd(NO(3))(2)(C(5)H(5)N(3)O)(2)(H(2)O)(2)]·2C(5)H(5)N(3)O, the Cd(II) cation is located on a twofold rotation axis and is coordinated by two pyrazine-2-carboxamide ligands and two water mol­ecules and chelated by two nitrate anions in a distorted square-anti­prismatic geometry...

Descripción completa

Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393246/
https://www.ncbi.nlm.nih.gov/pubmed/22807706
http://dx.doi.org/10.1107/S1600536812028577
_version_ 1782237704872787968
author Shirvan, Sadif A.
Haydari Dezfuli, Sara
author_facet Shirvan, Sadif A.
Haydari Dezfuli, Sara
author_sort Shirvan, Sadif A.
collection PubMed
description In the title compound, [Cd(NO(3))(2)(C(5)H(5)N(3)O)(2)(H(2)O)(2)]·2C(5)H(5)N(3)O, the Cd(II) cation is located on a twofold rotation axis and is coordinated by two pyrazine-2-carboxamide ligands and two water mol­ecules and chelated by two nitrate anions in a distorted square-anti­prismatic geometry. Extensive inter­molecular N—H⋯O, N—H⋯N, O—H⋯O and O—H⋯N hydrogen bonds, as well as weak inter­molecular C—H⋯N and C—H⋯O inter­actions occur in the crystal. π–π stacking between between pyrazine rings of coordinating ligands and lattice molecules [centroid–centroid distance = 3.5669 (14) Å] may further stabilize the structure.
format Online
Article
Text
id pubmed-3393246
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33932462012-07-17 Diaqua­bis­(nitrato-κ(2) O,O′)bis­(pyrazine-2-carboxamide-κN (4))cadmium–pyrazine-2-carboxamide (1/2) Shirvan, Sadif A. Haydari Dezfuli, Sara Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(NO(3))(2)(C(5)H(5)N(3)O)(2)(H(2)O)(2)]·2C(5)H(5)N(3)O, the Cd(II) cation is located on a twofold rotation axis and is coordinated by two pyrazine-2-carboxamide ligands and two water mol­ecules and chelated by two nitrate anions in a distorted square-anti­prismatic geometry. Extensive inter­molecular N—H⋯O, N—H⋯N, O—H⋯O and O—H⋯N hydrogen bonds, as well as weak inter­molecular C—H⋯N and C—H⋯O inter­actions occur in the crystal. π–π stacking between between pyrazine rings of coordinating ligands and lattice molecules [centroid–centroid distance = 3.5669 (14) Å] may further stabilize the structure. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393246/ /pubmed/22807706 http://dx.doi.org/10.1107/S1600536812028577 Text en © Shirvan and Haydari Dezfuli 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shirvan, Sadif A.
Haydari Dezfuli, Sara
Diaqua­bis­(nitrato-κ(2) O,O′)bis­(pyrazine-2-carboxamide-κN (4))cadmium–pyrazine-2-carboxamide (1/2)
title Diaqua­bis­(nitrato-κ(2) O,O′)bis­(pyrazine-2-carboxamide-κN (4))cadmium–pyrazine-2-carboxamide (1/2)
title_full Diaqua­bis­(nitrato-κ(2) O,O′)bis­(pyrazine-2-carboxamide-κN (4))cadmium–pyrazine-2-carboxamide (1/2)
title_fullStr Diaqua­bis­(nitrato-κ(2) O,O′)bis­(pyrazine-2-carboxamide-κN (4))cadmium–pyrazine-2-carboxamide (1/2)
title_full_unstemmed Diaqua­bis­(nitrato-κ(2) O,O′)bis­(pyrazine-2-carboxamide-κN (4))cadmium–pyrazine-2-carboxamide (1/2)
title_short Diaqua­bis­(nitrato-κ(2) O,O′)bis­(pyrazine-2-carboxamide-κN (4))cadmium–pyrazine-2-carboxamide (1/2)
title_sort diaqua­bis­(nitrato-κ(2) o,o′)bis­(pyrazine-2-carboxamide-κn (4))cadmium–pyrazine-2-carboxamide (1/2)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393246/
https://www.ncbi.nlm.nih.gov/pubmed/22807706
http://dx.doi.org/10.1107/S1600536812028577
work_keys_str_mv AT shirvansadifa diaquabisnitratok2oobispyrazine2carboxamidekn4cadmiumpyrazine2carboxamide12
AT haydaridezfulisara diaquabisnitratok2oobispyrazine2carboxamidekn4cadmiumpyrazine2carboxamide12