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Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))copper(II)

In the title complex, [Cu(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cu(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate (FB) anions, two nicotinamide (NA) ligands and two water mol­ecules in an elongated distorted octa­hedral geometry. The dihedral an...

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Detalles Bibliográficos
Autores principales: Sertçelik, Mustafa, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393247/
https://www.ncbi.nlm.nih.gov/pubmed/22807707
http://dx.doi.org/10.1107/S1600536812028814
Descripción
Sumario:In the title complex, [Cu(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cu(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate (FB) anions, two nicotinamide (NA) ligands and two water mol­ecules in an elongated distorted octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 23.00 (10)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 85.34 (4)°. An intra­molecular O—H⋯O hydrogen bond occurs between coordinating water mol­ecule and the carboxyl­ate group. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. A weak C—H⋯π inter­action also occurs in the crystal.