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Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))copper(II)

In the title complex, [Cu(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cu(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate (FB) anions, two nicotinamide (NA) ligands and two water mol­ecules in an elongated distorted octa­hedral geometry. The dihedral an...

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Autores principales: Sertçelik, Mustafa, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393247/
https://www.ncbi.nlm.nih.gov/pubmed/22807707
http://dx.doi.org/10.1107/S1600536812028814
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author Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Sertçelik, Mustafa
collection PubMed
description In the title complex, [Cu(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cu(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate (FB) anions, two nicotinamide (NA) ligands and two water mol­ecules in an elongated distorted octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 23.00 (10)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 85.34 (4)°. An intra­molecular O—H⋯O hydrogen bond occurs between coordinating water mol­ecule and the carboxyl­ate group. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. A weak C—H⋯π inter­action also occurs in the crystal.
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spelling pubmed-33932472012-07-17 Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))copper(II) Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cu(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate (FB) anions, two nicotinamide (NA) ligands and two water mol­ecules in an elongated distorted octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 23.00 (10)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 85.34 (4)°. An intra­molecular O—H⋯O hydrogen bond occurs between coordinating water mol­ecule and the carboxyl­ate group. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. A weak C—H⋯π inter­action also occurs in the crystal. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393247/ /pubmed/22807707 http://dx.doi.org/10.1107/S1600536812028814 Text en © Sertçelik et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))copper(II)
title Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))copper(II)
title_full Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))copper(II)
title_fullStr Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))copper(II)
title_full_unstemmed Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))copper(II)
title_short Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))copper(II)
title_sort diaqua­bis­(4-formyl­benzoato-κo (1))bis­(nicotinamide-κn (1))copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393247/
https://www.ncbi.nlm.nih.gov/pubmed/22807707
http://dx.doi.org/10.1107/S1600536812028814
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