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Diaquabis(4-formylbenzoato-κO (1))bis(nicotinamide-κN (1))copper(II)
In the title complex, [Cu(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cu(II) cation is located on an inversion center and is coordinated by two 4-formylbenzoate (FB) anions, two nicotinamide (NA) ligands and two water molecules in an elongated distorted octahedral geometry. The dihedral an...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393247/ https://www.ncbi.nlm.nih.gov/pubmed/22807707 http://dx.doi.org/10.1107/S1600536812028814 |
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author | Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Sertçelik, Mustafa |
collection | PubMed |
description | In the title complex, [Cu(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cu(II) cation is located on an inversion center and is coordinated by two 4-formylbenzoate (FB) anions, two nicotinamide (NA) ligands and two water molecules in an elongated distorted octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 23.00 (10)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 85.34 (4)°. An intramolecular O—H⋯O hydrogen bond occurs between coordinating water molecule and the carboxylate group. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular network. A weak C—H⋯π interaction also occurs in the crystal. |
format | Online Article Text |
id | pubmed-3393247 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33932472012-07-17 Diaquabis(4-formylbenzoato-κO (1))bis(nicotinamide-κN (1))copper(II) Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cu(II) cation is located on an inversion center and is coordinated by two 4-formylbenzoate (FB) anions, two nicotinamide (NA) ligands and two water molecules in an elongated distorted octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 23.00 (10)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 85.34 (4)°. An intramolecular O—H⋯O hydrogen bond occurs between coordinating water molecule and the carboxylate group. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular network. A weak C—H⋯π interaction also occurs in the crystal. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393247/ /pubmed/22807707 http://dx.doi.org/10.1107/S1600536812028814 Text en © Sertçelik et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Diaquabis(4-formylbenzoato-κO (1))bis(nicotinamide-κN (1))copper(II) |
title | Diaquabis(4-formylbenzoato-κO
(1))bis(nicotinamide-κN
(1))copper(II) |
title_full | Diaquabis(4-formylbenzoato-κO
(1))bis(nicotinamide-κN
(1))copper(II) |
title_fullStr | Diaquabis(4-formylbenzoato-κO
(1))bis(nicotinamide-κN
(1))copper(II) |
title_full_unstemmed | Diaquabis(4-formylbenzoato-κO
(1))bis(nicotinamide-κN
(1))copper(II) |
title_short | Diaquabis(4-formylbenzoato-κO
(1))bis(nicotinamide-κN
(1))copper(II) |
title_sort | diaquabis(4-formylbenzoato-κo
(1))bis(nicotinamide-κn
(1))copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393247/ https://www.ncbi.nlm.nih.gov/pubmed/22807707 http://dx.doi.org/10.1107/S1600536812028814 |
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