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Bis(ethylenediamine-κ(2) N,N′)bis(methanol-κO)copper(II) benzene-1,4-dicarboxylate methanol disolvate
In the cation of the title compound, [Cu(C(2)H(8)N(2))(2)(CH(3)OH)(2)](C(8)H(4)O(4))·2CH(3)OH, the Cu(II) atom lies on an inversion centre. The four N atoms of two ethylenediamine ligands around the Cu(II) atom form the equatorial plane, while two methanol O atoms in the axial positions complete a...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393248/ https://www.ncbi.nlm.nih.gov/pubmed/22807708 http://dx.doi.org/10.1107/S1600536812028942 |
Sumario: | In the cation of the title compound, [Cu(C(2)H(8)N(2))(2)(CH(3)OH)(2)](C(8)H(4)O(4))·2CH(3)OH, the Cu(II) atom lies on an inversion centre. The four N atoms of two ethylenediamine ligands around the Cu(II) atom form the equatorial plane, while two methanol O atoms in the axial positions complete a Jahn–Teller distorted octahedral coordination. The benzene-1,4-dicarboxylate anion is centrosymmetric. In the crystal, C—H⋯O, N—H⋯O and O—H⋯O hydrogen bonds link the cations, the anions and the methanol solvent molecules. |
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