Bis(ethyl­enediamine-κ(2) N,N′)bis­(methanol-κO)copper(II) benzene-1,4-dicarboxyl­ate methanol disolvate

In the cation of the title compound, [Cu(C(2)H(8)N(2))(2)(CH(3)OH)(2)](C(8)H(4)O(4))·2CH(3)OH, the Cu(II) atom lies on an inversion centre. The four N atoms of two ethyl­enediamine ligands around the Cu(II) atom form the equatorial plane, while two methanol O atoms in the axial positions complete a...

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Autores principales: Abbaszadeh, Abolfazl, Safari, Nasser, Amani, Vahid, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393248/
https://www.ncbi.nlm.nih.gov/pubmed/22807708
http://dx.doi.org/10.1107/S1600536812028942
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author Abbaszadeh, Abolfazl
Safari, Nasser
Amani, Vahid
Notash, Behrouz
author_facet Abbaszadeh, Abolfazl
Safari, Nasser
Amani, Vahid
Notash, Behrouz
author_sort Abbaszadeh, Abolfazl
collection PubMed
description In the cation of the title compound, [Cu(C(2)H(8)N(2))(2)(CH(3)OH)(2)](C(8)H(4)O(4))·2CH(3)OH, the Cu(II) atom lies on an inversion centre. The four N atoms of two ethyl­enediamine ligands around the Cu(II) atom form the equatorial plane, while two methanol O atoms in the axial positions complete a Jahn–Teller distorted octa­hedral coordination. The benzene-1,4-dicarboxyl­ate anion is centrosymmetric. In the crystal, C—H⋯O, N—H⋯O and O—H⋯O hydrogen bonds link the cations, the anions and the methanol solvent mol­ecules.
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spelling pubmed-33932482012-07-17 Bis(ethyl­enediamine-κ(2) N,N′)bis­(methanol-κO)copper(II) benzene-1,4-dicarboxyl­ate methanol disolvate Abbaszadeh, Abolfazl Safari, Nasser Amani, Vahid Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Cu(C(2)H(8)N(2))(2)(CH(3)OH)(2)](C(8)H(4)O(4))·2CH(3)OH, the Cu(II) atom lies on an inversion centre. The four N atoms of two ethyl­enediamine ligands around the Cu(II) atom form the equatorial plane, while two methanol O atoms in the axial positions complete a Jahn–Teller distorted octa­hedral coordination. The benzene-1,4-dicarboxyl­ate anion is centrosymmetric. In the crystal, C—H⋯O, N—H⋯O and O—H⋯O hydrogen bonds link the cations, the anions and the methanol solvent mol­ecules. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393248/ /pubmed/22807708 http://dx.doi.org/10.1107/S1600536812028942 Text en © Abbaszadeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Abbaszadeh, Abolfazl
Safari, Nasser
Amani, Vahid
Notash, Behrouz
Bis(ethyl­enediamine-κ(2) N,N′)bis­(methanol-κO)copper(II) benzene-1,4-dicarboxyl­ate methanol disolvate
title Bis(ethyl­enediamine-κ(2) N,N′)bis­(methanol-κO)copper(II) benzene-1,4-dicarboxyl­ate methanol disolvate
title_full Bis(ethyl­enediamine-κ(2) N,N′)bis­(methanol-κO)copper(II) benzene-1,4-dicarboxyl­ate methanol disolvate
title_fullStr Bis(ethyl­enediamine-κ(2) N,N′)bis­(methanol-κO)copper(II) benzene-1,4-dicarboxyl­ate methanol disolvate
title_full_unstemmed Bis(ethyl­enediamine-κ(2) N,N′)bis­(methanol-κO)copper(II) benzene-1,4-dicarboxyl­ate methanol disolvate
title_short Bis(ethyl­enediamine-κ(2) N,N′)bis­(methanol-κO)copper(II) benzene-1,4-dicarboxyl­ate methanol disolvate
title_sort bis(ethyl­enediamine-κ(2) n,n′)bis­(methanol-κo)copper(ii) benzene-1,4-dicarboxyl­ate methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393248/
https://www.ncbi.nlm.nih.gov/pubmed/22807708
http://dx.doi.org/10.1107/S1600536812028942
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