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([2.2.2]Cryptand-κ(6) O)potassium (η(4)-cyclooctadiene)bis(η(2)-pyrene)cobaltate(1−) pentane hemisolvate
The cation, anion, and solvent in the title compound, [K(C(18)H(36)N(2)O(6))][Co(C(8)H(12))(C(16)H(10))(2)]·0.5C(5)H(12), are well separated. The pentane solvent molecules are found in channels along [100] and were modeled as disordered over crystallographic inversion centers. Using the mid-points...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393249/ https://www.ncbi.nlm.nih.gov/pubmed/22807709 http://dx.doi.org/10.1107/S1600536812029078 |
| _version_ | 1782237705587916800 |
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| author | Brennessel, William W. Ellis, John E. |
| author_facet | Brennessel, William W. Ellis, John E. |
| author_sort | Brennessel, William W. |
| collection | PubMed |
| description | The cation, anion, and solvent in the title compound, [K(C(18)H(36)N(2)O(6))][Co(C(8)H(12))(C(16)H(10))(2)]·0.5C(5)H(12), are well separated. The pentane solvent molecules are found in channels along [100] and were modeled as disordered over crystallographic inversion centers. Using the mid-points of the coordinated olefins, the angle between the C(py)/C(py)–Co–C(py)/C(py) and the C(cod)/C(cod)–Co–C(cod)/C(cod) planes (py is pyrene and cod is cyclooctadiene) is 67.6 (2)°. Thus, the overall geometry of the coordination sphere around cobalt is best described as distorted tetrahedral. |
| format | Online Article Text |
| id | pubmed-3393249 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33932492012-07-17 ([2.2.2]Cryptand-κ(6) O)potassium (η(4)-cyclooctadiene)bis(η(2)-pyrene)cobaltate(1−) pentane hemisolvate Brennessel, William W. Ellis, John E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The cation, anion, and solvent in the title compound, [K(C(18)H(36)N(2)O(6))][Co(C(8)H(12))(C(16)H(10))(2)]·0.5C(5)H(12), are well separated. The pentane solvent molecules are found in channels along [100] and were modeled as disordered over crystallographic inversion centers. Using the mid-points of the coordinated olefins, the angle between the C(py)/C(py)–Co–C(py)/C(py) and the C(cod)/C(cod)–Co–C(cod)/C(cod) planes (py is pyrene and cod is cyclooctadiene) is 67.6 (2)°. Thus, the overall geometry of the coordination sphere around cobalt is best described as distorted tetrahedral. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393249/ /pubmed/22807709 http://dx.doi.org/10.1107/S1600536812029078 Text en © Brennessel and Ellis 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Brennessel, William W. Ellis, John E. ([2.2.2]Cryptand-κ(6) O)potassium (η(4)-cyclooctadiene)bis(η(2)-pyrene)cobaltate(1−) pentane hemisolvate |
| title | ([2.2.2]Cryptand-κ(6)
O)potassium (η(4)-cyclooctadiene)bis(η(2)-pyrene)cobaltate(1−) pentane hemisolvate |
| title_full | ([2.2.2]Cryptand-κ(6)
O)potassium (η(4)-cyclooctadiene)bis(η(2)-pyrene)cobaltate(1−) pentane hemisolvate |
| title_fullStr | ([2.2.2]Cryptand-κ(6)
O)potassium (η(4)-cyclooctadiene)bis(η(2)-pyrene)cobaltate(1−) pentane hemisolvate |
| title_full_unstemmed | ([2.2.2]Cryptand-κ(6)
O)potassium (η(4)-cyclooctadiene)bis(η(2)-pyrene)cobaltate(1−) pentane hemisolvate |
| title_short | ([2.2.2]Cryptand-κ(6)
O)potassium (η(4)-cyclooctadiene)bis(η(2)-pyrene)cobaltate(1−) pentane hemisolvate |
| title_sort | ([2.2.2]cryptand-κ(6)
o)potassium (η(4)-cyclooctadiene)bis(η(2)-pyrene)cobaltate(1−) pentane hemisolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393249/ https://www.ncbi.nlm.nih.gov/pubmed/22807709 http://dx.doi.org/10.1107/S1600536812029078 |
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