Dimethyl­ammonium dichloridotriphenyl­stannate(IV)

The title salt, [(CH(3))(2)NH(2)][Sn(C(6)H(5))(3)Cl(2)], was obtained as a by-product of the reaction between bis­(dimethyl­ammonium) oxalate and triphenyl­tin chloride. In the stannate anion, the trigonal–bipyramidal coordination environment of the Sn(IV) atom is defined by the phenyl groups in equ...

Descripción completa

Detalles Bibliográficos
Autores principales: Sow, Yaya, Diop, Libasse, Kociok-Kohn, Gabriele, Molloy, Kieran C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393250/
https://www.ncbi.nlm.nih.gov/pubmed/22807710
http://dx.doi.org/10.1107/S1600536812028905
Descripción
Sumario:The title salt, [(CH(3))(2)NH(2)][Sn(C(6)H(5))(3)Cl(2)], was obtained as a by-product of the reaction between bis­(dimethyl­ammonium) oxalate and triphenyl­tin chloride. In the stannate anion, the trigonal–bipyramidal coordination environment of the Sn(IV) atom is defined by the phenyl groups in equatorial and the Cl atoms in axial positions. The cations are connected to adjacent anions through N—H⋯Cl and C—H⋯Cl hydrogen-bonding inter­actions, leading to a chain motif parallel to [100].

Ejemplares similares