Dimethyl­ammonium dichloridotriphenyl­stannate(IV)

The title salt, [(CH(3))(2)NH(2)][Sn(C(6)H(5))(3)Cl(2)], was obtained as a by-product of the reaction between bis­(dimethyl­ammonium) oxalate and triphenyl­tin chloride. In the stannate anion, the trigonal–bipyramidal coordination environment of the Sn(IV) atom is defined by the phenyl groups in equ...

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Autores principales: Sow, Yaya, Diop, Libasse, Kociok-Kohn, Gabriele, Molloy, Kieran C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393250/
https://www.ncbi.nlm.nih.gov/pubmed/22807710
http://dx.doi.org/10.1107/S1600536812028905
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author Sow, Yaya
Diop, Libasse
Kociok-Kohn, Gabriele
Molloy, Kieran C.
author_facet Sow, Yaya
Diop, Libasse
Kociok-Kohn, Gabriele
Molloy, Kieran C.
author_sort Sow, Yaya
collection PubMed
description The title salt, [(CH(3))(2)NH(2)][Sn(C(6)H(5))(3)Cl(2)], was obtained as a by-product of the reaction between bis­(dimethyl­ammonium) oxalate and triphenyl­tin chloride. In the stannate anion, the trigonal–bipyramidal coordination environment of the Sn(IV) atom is defined by the phenyl groups in equatorial and the Cl atoms in axial positions. The cations are connected to adjacent anions through N—H⋯Cl and C—H⋯Cl hydrogen-bonding inter­actions, leading to a chain motif parallel to [100].
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spelling pubmed-33932502012-07-17 Dimethyl­ammonium dichloridotriphenyl­stannate(IV) Sow, Yaya Diop, Libasse Kociok-Kohn, Gabriele Molloy, Kieran C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title salt, [(CH(3))(2)NH(2)][Sn(C(6)H(5))(3)Cl(2)], was obtained as a by-product of the reaction between bis­(dimethyl­ammonium) oxalate and triphenyl­tin chloride. In the stannate anion, the trigonal–bipyramidal coordination environment of the Sn(IV) atom is defined by the phenyl groups in equatorial and the Cl atoms in axial positions. The cations are connected to adjacent anions through N—H⋯Cl and C—H⋯Cl hydrogen-bonding inter­actions, leading to a chain motif parallel to [100]. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393250/ /pubmed/22807710 http://dx.doi.org/10.1107/S1600536812028905 Text en © Sow et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sow, Yaya
Diop, Libasse
Kociok-Kohn, Gabriele
Molloy, Kieran C.
Dimethyl­ammonium dichloridotriphenyl­stannate(IV)
title Dimethyl­ammonium dichloridotriphenyl­stannate(IV)
title_full Dimethyl­ammonium dichloridotriphenyl­stannate(IV)
title_fullStr Dimethyl­ammonium dichloridotriphenyl­stannate(IV)
title_full_unstemmed Dimethyl­ammonium dichloridotriphenyl­stannate(IV)
title_short Dimethyl­ammonium dichloridotriphenyl­stannate(IV)
title_sort dimethyl­ammonium dichloridotriphenyl­stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393250/
https://www.ncbi.nlm.nih.gov/pubmed/22807710
http://dx.doi.org/10.1107/S1600536812028905
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AT dioplibasse dimethylammoniumdichloridotriphenylstannateiv
AT kociokkohngabriele dimethylammoniumdichloridotriphenylstannateiv
AT molloykieranc dimethylammoniumdichloridotriphenylstannateiv

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