catena-Poly[{μ(3)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methan­ylyl­idene)]diphenolato}{μ(2)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]dipheno­lato}dicopper(II)]

The asymmetric unit of the title coordination polymer consists of a dinuclear neutral complex mol­ecule of formula [Cu(2)(C(18)H(14)Br(4)N(2)O(2))(2)](n). One of the Cu(II) ions is coordinated in a distorted square-planar geometry, whereas the other is coordinated in a distorted square-pyramidal geo...

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Autores principales: Kargar, Hadi, Kia, Reza, Adabi Ardakani, Amir, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393252/
https://www.ncbi.nlm.nih.gov/pubmed/22807712
http://dx.doi.org/10.1107/S1600536812029285
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author Kargar, Hadi
Kia, Reza
Adabi Ardakani, Amir
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Adabi Ardakani, Amir
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description The asymmetric unit of the title coordination polymer consists of a dinuclear neutral complex mol­ecule of formula [Cu(2)(C(18)H(14)Br(4)N(2)O(2))(2)](n). One of the Cu(II) ions is coordinated in a distorted square-planar geometry, whereas the other is coordinated in a distorted square-pyramidal geometry, the long apical Cu—O bond [2.885 (4) Å] of the square-pyramidal coordination being provided by a symmetry-related O atom creating a one-dimensional polymer along [010]. π–π stacking inter­actions [centroid–centroid distance = 3.783 (4) Å] and short inter­chain Br⋯Br inter­actions [3.6142 (12)–3.6797 (12) Å] are observed.
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spelling pubmed-33932522012-07-17 catena-Poly[{μ(3)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methan­ylyl­idene)]diphenolato}{μ(2)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]dipheno­lato}dicopper(II)] Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title coordination polymer consists of a dinuclear neutral complex mol­ecule of formula [Cu(2)(C(18)H(14)Br(4)N(2)O(2))(2)](n). One of the Cu(II) ions is coordinated in a distorted square-planar geometry, whereas the other is coordinated in a distorted square-pyramidal geometry, the long apical Cu—O bond [2.885 (4) Å] of the square-pyramidal coordination being provided by a symmetry-related O atom creating a one-dimensional polymer along [010]. π–π stacking inter­actions [centroid–centroid distance = 3.783 (4) Å] and short inter­chain Br⋯Br inter­actions [3.6142 (12)–3.6797 (12) Å] are observed. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393252/ /pubmed/22807712 http://dx.doi.org/10.1107/S1600536812029285 Text en © Kia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
Adabi Ardakani, Amir
Tahir, Muhammad Nawaz
catena-Poly[{μ(3)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methan­ylyl­idene)]diphenolato}{μ(2)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]dipheno­lato}dicopper(II)]
title catena-Poly[{μ(3)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methan­ylyl­idene)]diphenolato}{μ(2)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]dipheno­lato}dicopper(II)]
title_full catena-Poly[{μ(3)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methan­ylyl­idene)]diphenolato}{μ(2)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]dipheno­lato}dicopper(II)]
title_fullStr catena-Poly[{μ(3)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methan­ylyl­idene)]diphenolato}{μ(2)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]dipheno­lato}dicopper(II)]
title_full_unstemmed catena-Poly[{μ(3)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methan­ylyl­idene)]diphenolato}{μ(2)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]dipheno­lato}dicopper(II)]
title_short catena-Poly[{μ(3)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methan­ylyl­idene)]diphenolato}{μ(2)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]dipheno­lato}dicopper(II)]
title_sort catena-poly[{μ(3)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methan­ylyl­idene)]diphenolato}{μ(2)-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­idene)]dipheno­lato}dicopper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393252/
https://www.ncbi.nlm.nih.gov/pubmed/22807712
http://dx.doi.org/10.1107/S1600536812029285
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