1-Dichloro­acetyl-8a-methyl-1,2,3,4,6,7,8,8a-octa­hydro­pyrrolo­[1,2-a]pyrimidin-6-one

In the title compound, C(10)H(14)Cl(2)N(2)O(2), the five-membered ring adopts an envelope conformation (with the methylene C atom closest to the C—N bridge as the flap), while the conformation of the six-membered ring is close to a twist-boat. In the crystal, mol­ecules are linked by weak C—H⋯O hydr...

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Detalles Bibliográficos
Autores principales: Gao, Shuang, Zhao, Li-xia, Ye, Fei, Fu, Ying, Xing, Zhi-yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393258/
https://www.ncbi.nlm.nih.gov/pubmed/22807815
http://dx.doi.org/10.1107/S1600536812024063
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author Gao, Shuang
Zhao, Li-xia
Ye, Fei
Fu, Ying
Xing, Zhi-yong
author_facet Gao, Shuang
Zhao, Li-xia
Ye, Fei
Fu, Ying
Xing, Zhi-yong
author_sort Gao, Shuang
collection PubMed
description In the title compound, C(10)H(14)Cl(2)N(2)O(2), the five-membered ring adopts an envelope conformation (with the methylene C atom closest to the C—N bridge as the flap), while the conformation of the six-membered ring is close to a twist-boat. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming chains along the c-axis direction.
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spelling pubmed-33932582012-07-17 1-Dichloro­acetyl-8a-methyl-1,2,3,4,6,7,8,8a-octa­hydro­pyrrolo­[1,2-a]pyrimidin-6-one Gao, Shuang Zhao, Li-xia Ye, Fei Fu, Ying Xing, Zhi-yong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(14)Cl(2)N(2)O(2), the five-membered ring adopts an envelope conformation (with the methylene C atom closest to the C—N bridge as the flap), while the conformation of the six-membered ring is close to a twist-boat. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming chains along the c-axis direction. International Union of Crystallography 2012-06-02 /pmc/articles/PMC3393258/ /pubmed/22807815 http://dx.doi.org/10.1107/S1600536812024063 Text en © Gao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gao, Shuang
Zhao, Li-xia
Ye, Fei
Fu, Ying
Xing, Zhi-yong
1-Dichloro­acetyl-8a-methyl-1,2,3,4,6,7,8,8a-octa­hydro­pyrrolo­[1,2-a]pyrimidin-6-one
title 1-Dichloro­acetyl-8a-methyl-1,2,3,4,6,7,8,8a-octa­hydro­pyrrolo­[1,2-a]pyrimidin-6-one
title_full 1-Dichloro­acetyl-8a-methyl-1,2,3,4,6,7,8,8a-octa­hydro­pyrrolo­[1,2-a]pyrimidin-6-one
title_fullStr 1-Dichloro­acetyl-8a-methyl-1,2,3,4,6,7,8,8a-octa­hydro­pyrrolo­[1,2-a]pyrimidin-6-one
title_full_unstemmed 1-Dichloro­acetyl-8a-methyl-1,2,3,4,6,7,8,8a-octa­hydro­pyrrolo­[1,2-a]pyrimidin-6-one
title_short 1-Dichloro­acetyl-8a-methyl-1,2,3,4,6,7,8,8a-octa­hydro­pyrrolo­[1,2-a]pyrimidin-6-one
title_sort 1-dichloro­acetyl-8a-methyl-1,2,3,4,6,7,8,8a-octa­hydro­pyrrolo­[1,2-a]pyrimidin-6-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393258/
https://www.ncbi.nlm.nih.gov/pubmed/22807815
http://dx.doi.org/10.1107/S1600536812024063
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