N,N′-{[Ethane-1,2-diylbis(­oxy)]bis­(ethane-2,1-di­yl)}bis­(4-methyl­benzene­sulfonamide)

The asymmetric unit of the title compound, C(20)H(28)N(2)O(6)S(2), contains one half-mol­ecule, related to the other half by a twofold rotation axis. The two aromatic rings of the mol­ecule make a dihedral angle of 50.91 (7)°. The O—CH(2)—CH(2)—O and N—CH(2)—CH(2)—O fragments both adopt gauche confo...

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Autores principales: Al-Mohammed, Nassir N., Alias, Yatimah, Abdullah, Zanariah, Khaledi, Hamid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393259/
https://www.ncbi.nlm.nih.gov/pubmed/22807816
http://dx.doi.org/10.1107/S1600536812024324
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author Al-Mohammed, Nassir N.
Alias, Yatimah
Abdullah, Zanariah
Khaledi, Hamid
author_facet Al-Mohammed, Nassir N.
Alias, Yatimah
Abdullah, Zanariah
Khaledi, Hamid
author_sort Al-Mohammed, Nassir N.
collection PubMed
description The asymmetric unit of the title compound, C(20)H(28)N(2)O(6)S(2), contains one half-mol­ecule, related to the other half by a twofold rotation axis. The two aromatic rings of the mol­ecule make a dihedral angle of 50.91 (7)°. The O—CH(2)—CH(2)—O and N—CH(2)—CH(2)—O fragments both adopt gauche conformations, with torsion angles of 76.0 (4) and 70.4 (3)°, respectively. In the crystal, adjacent mol­ecules are linked through N—H⋯O hydrogen bonds into chains along the a-axis direction. The chains are further connected via C—H⋯O inter­actions into a two-dimensional supra­molecular network in the ac plane.
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spelling pubmed-33932592012-07-17 N,N′-{[Ethane-1,2-diylbis(­oxy)]bis­(ethane-2,1-di­yl)}bis­(4-methyl­benzene­sulfonamide) Al-Mohammed, Nassir N. Alias, Yatimah Abdullah, Zanariah Khaledi, Hamid Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(20)H(28)N(2)O(6)S(2), contains one half-mol­ecule, related to the other half by a twofold rotation axis. The two aromatic rings of the mol­ecule make a dihedral angle of 50.91 (7)°. The O—CH(2)—CH(2)—O and N—CH(2)—CH(2)—O fragments both adopt gauche conformations, with torsion angles of 76.0 (4) and 70.4 (3)°, respectively. In the crystal, adjacent mol­ecules are linked through N—H⋯O hydrogen bonds into chains along the a-axis direction. The chains are further connected via C—H⋯O inter­actions into a two-dimensional supra­molecular network in the ac plane. International Union of Crystallography 2012-06-02 /pmc/articles/PMC3393259/ /pubmed/22807816 http://dx.doi.org/10.1107/S1600536812024324 Text en © Al-Mohammed et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Al-Mohammed, Nassir N.
Alias, Yatimah
Abdullah, Zanariah
Khaledi, Hamid
N,N′-{[Ethane-1,2-diylbis(­oxy)]bis­(ethane-2,1-di­yl)}bis­(4-methyl­benzene­sulfonamide)
title N,N′-{[Ethane-1,2-diylbis(­oxy)]bis­(ethane-2,1-di­yl)}bis­(4-methyl­benzene­sulfonamide)
title_full N,N′-{[Ethane-1,2-diylbis(­oxy)]bis­(ethane-2,1-di­yl)}bis­(4-methyl­benzene­sulfonamide)
title_fullStr N,N′-{[Ethane-1,2-diylbis(­oxy)]bis­(ethane-2,1-di­yl)}bis­(4-methyl­benzene­sulfonamide)
title_full_unstemmed N,N′-{[Ethane-1,2-diylbis(­oxy)]bis­(ethane-2,1-di­yl)}bis­(4-methyl­benzene­sulfonamide)
title_short N,N′-{[Ethane-1,2-diylbis(­oxy)]bis­(ethane-2,1-di­yl)}bis­(4-methyl­benzene­sulfonamide)
title_sort n,n′-{[ethane-1,2-diylbis(­oxy)]bis­(ethane-2,1-di­yl)}bis­(4-methyl­benzene­sulfonamide)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393259/
https://www.ncbi.nlm.nih.gov/pubmed/22807816
http://dx.doi.org/10.1107/S1600536812024324
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AT abdullahzanariah nnethane12diylbisoxybisethane21diylbis4methylbenzenesulfonamide
AT khaledihamid nnethane12diylbisoxybisethane21diylbis4methylbenzenesulfonamide

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