4-Methyl­anilinium 2-carb­oxy­acetate

During the formation of the title salt, C(7)H(10)N(+)·C(3)H(3)O(4) (−), an H atom of a carboxyl group was transferred to the amino group. All non-H atoms of the cation are essentially coplanar [r.m.s. deviation = 0.007 (4) Å]. The mean planes of the carboxyl­ate and carboxyl groups of the anion form...

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Autor principal: Wang, Ying-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393260/
https://www.ncbi.nlm.nih.gov/pubmed/22807817
http://dx.doi.org/10.1107/S1600536812024403
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author Wang, Ying-Chun
author_facet Wang, Ying-Chun
author_sort Wang, Ying-Chun
collection PubMed
description During the formation of the title salt, C(7)H(10)N(+)·C(3)H(3)O(4) (−), an H atom of a carboxyl group was transferred to the amino group. All non-H atoms of the cation are essentially coplanar [r.m.s. deviation = 0.007 (4) Å]. The mean planes of the carboxyl­ate and carboxyl groups of the anion form a dihedral of 69.67 (1)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds connect the anions and cations, forming a two-dimensional network parallel to the bc plane.
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spelling pubmed-33932602012-07-17 4-Methyl­anilinium 2-carb­oxy­acetate Wang, Ying-Chun Acta Crystallogr Sect E Struct Rep Online Organic Papers During the formation of the title salt, C(7)H(10)N(+)·C(3)H(3)O(4) (−), an H atom of a carboxyl group was transferred to the amino group. All non-H atoms of the cation are essentially coplanar [r.m.s. deviation = 0.007 (4) Å]. The mean planes of the carboxyl­ate and carboxyl groups of the anion form a dihedral of 69.67 (1)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds connect the anions and cations, forming a two-dimensional network parallel to the bc plane. International Union of Crystallography 2012-06-02 /pmc/articles/PMC3393260/ /pubmed/22807817 http://dx.doi.org/10.1107/S1600536812024403 Text en © Ying-Chun Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Ying-Chun
4-Methyl­anilinium 2-carb­oxy­acetate
title 4-Methyl­anilinium 2-carb­oxy­acetate
title_full 4-Methyl­anilinium 2-carb­oxy­acetate
title_fullStr 4-Methyl­anilinium 2-carb­oxy­acetate
title_full_unstemmed 4-Methyl­anilinium 2-carb­oxy­acetate
title_short 4-Methyl­anilinium 2-carb­oxy­acetate
title_sort 4-methyl­anilinium 2-carb­oxy­acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393260/
https://www.ncbi.nlm.nih.gov/pubmed/22807817
http://dx.doi.org/10.1107/S1600536812024403
work_keys_str_mv AT wangyingchun 4methylanilinium2carboxyacetate

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