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(Z)-3-(4-Bromophenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one
The title compound, C(21)H(19)BrN(2)OS, exists in a cis conformation with respect to the N=C bond [1.2602 (14) Å]. The cyclohexene ring adopts a distorted half-chair conformation and the C—N bond lies in an equatorial orientation. The thiazolidine ring forms dihedral angles of 53.76 (7) and 57.22 ...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393268/ https://www.ncbi.nlm.nih.gov/pubmed/22807825 http://dx.doi.org/10.1107/S1600536812024646 |
Sumario: | The title compound, C(21)H(19)BrN(2)OS, exists in a cis conformation with respect to the N=C bond [1.2602 (14) Å]. The cyclohexene ring adopts a distorted half-chair conformation and the C—N bond lies in an equatorial orientation. The thiazolidine ring forms dihedral angles of 53.76 (7) and 57.22 (7)° with the benzene and bromo-substituted benzene rings, respectively. The dihedral angle between the benzene and bromo-substituted benzene rings is 76.06 (7)°. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(14) loops. The crystal is further consolidated by weak C—H⋯π interactions. |
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