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(Z)-3-(4-Bromo­phen­yl)-2-[(2-phenyl­cyclo­hex-2-en-1-yl)imino]-1,3-thia­zol­idin-4-one

The title compound, C(21)H(19)BrN(2)OS, exists in a cis conformation with respect to the N=C bond [1.2602 (14) Å]. The cyclo­hexene ring adopts a distorted half-chair conformation and the C—N bond lies in an equatorial orientation. The thia­zolidine ring forms dihedral angles of 53.76 (7) and 57.22 ...

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Detalles Bibliográficos
Autores principales: Ooi, Chin Wei, Fun, Hoong-Kun, Quah, Ching Kheng, Sathishkumar, Murugan, Ponnuswamy, Alagusundaram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393268/
https://www.ncbi.nlm.nih.gov/pubmed/22807825
http://dx.doi.org/10.1107/S1600536812024646
Descripción
Sumario:The title compound, C(21)H(19)BrN(2)OS, exists in a cis conformation with respect to the N=C bond [1.2602 (14) Å]. The cyclo­hexene ring adopts a distorted half-chair conformation and the C—N bond lies in an equatorial orientation. The thia­zolidine ring forms dihedral angles of 53.76 (7) and 57.22 (7)° with the benzene and bromo-substituted benzene rings, respectively. The dihedral angle between the benzene and bromo-substituted benzene rings is 76.06 (7)°. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(14) loops. The crystal is further consolidated by weak C—H⋯π inter­actions.