(Z)-3-(4-Bromo­phen­yl)-2-[(2-phenyl­cyclo­hex-2-en-1-yl)imino]-1,3-thia­zol­idin-4-one

The title compound, C(21)H(19)BrN(2)OS, exists in a cis conformation with respect to the N=C bond [1.2602 (14) Å]. The cyclo­hexene ring adopts a distorted half-chair conformation and the C—N bond lies in an equatorial orientation. The thia­zolidine ring forms dihedral angles of 53.76 (7) and 57.22 ...

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Autores principales: Ooi, Chin Wei, Fun, Hoong-Kun, Quah, Ching Kheng, Sathishkumar, Murugan, Ponnuswamy, Alagusundaram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393268/
https://www.ncbi.nlm.nih.gov/pubmed/22807825
http://dx.doi.org/10.1107/S1600536812024646
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author Ooi, Chin Wei
Fun, Hoong-Kun
Quah, Ching Kheng
Sathishkumar, Murugan
Ponnuswamy, Alagusundaram
author_facet Ooi, Chin Wei
Fun, Hoong-Kun
Quah, Ching Kheng
Sathishkumar, Murugan
Ponnuswamy, Alagusundaram
author_sort Ooi, Chin Wei
collection PubMed
description The title compound, C(21)H(19)BrN(2)OS, exists in a cis conformation with respect to the N=C bond [1.2602 (14) Å]. The cyclo­hexene ring adopts a distorted half-chair conformation and the C—N bond lies in an equatorial orientation. The thia­zolidine ring forms dihedral angles of 53.76 (7) and 57.22 (7)° with the benzene and bromo-substituted benzene rings, respectively. The dihedral angle between the benzene and bromo-substituted benzene rings is 76.06 (7)°. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(14) loops. The crystal is further consolidated by weak C—H⋯π inter­actions.
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spelling pubmed-33932682012-07-17 (Z)-3-(4-Bromo­phen­yl)-2-[(2-phenyl­cyclo­hex-2-en-1-yl)imino]-1,3-thia­zol­idin-4-one Ooi, Chin Wei Fun, Hoong-Kun Quah, Ching Kheng Sathishkumar, Murugan Ponnuswamy, Alagusundaram Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(19)BrN(2)OS, exists in a cis conformation with respect to the N=C bond [1.2602 (14) Å]. The cyclo­hexene ring adopts a distorted half-chair conformation and the C—N bond lies in an equatorial orientation. The thia­zolidine ring forms dihedral angles of 53.76 (7) and 57.22 (7)° with the benzene and bromo-substituted benzene rings, respectively. The dihedral angle between the benzene and bromo-substituted benzene rings is 76.06 (7)°. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(14) loops. The crystal is further consolidated by weak C—H⋯π inter­actions. International Union of Crystallography 2012-06-02 /pmc/articles/PMC3393268/ /pubmed/22807825 http://dx.doi.org/10.1107/S1600536812024646 Text en © Ooi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ooi, Chin Wei
Fun, Hoong-Kun
Quah, Ching Kheng
Sathishkumar, Murugan
Ponnuswamy, Alagusundaram
(Z)-3-(4-Bromo­phen­yl)-2-[(2-phenyl­cyclo­hex-2-en-1-yl)imino]-1,3-thia­zol­idin-4-one
title (Z)-3-(4-Bromo­phen­yl)-2-[(2-phenyl­cyclo­hex-2-en-1-yl)imino]-1,3-thia­zol­idin-4-one
title_full (Z)-3-(4-Bromo­phen­yl)-2-[(2-phenyl­cyclo­hex-2-en-1-yl)imino]-1,3-thia­zol­idin-4-one
title_fullStr (Z)-3-(4-Bromo­phen­yl)-2-[(2-phenyl­cyclo­hex-2-en-1-yl)imino]-1,3-thia­zol­idin-4-one
title_full_unstemmed (Z)-3-(4-Bromo­phen­yl)-2-[(2-phenyl­cyclo­hex-2-en-1-yl)imino]-1,3-thia­zol­idin-4-one
title_short (Z)-3-(4-Bromo­phen­yl)-2-[(2-phenyl­cyclo­hex-2-en-1-yl)imino]-1,3-thia­zol­idin-4-one
title_sort (z)-3-(4-bromo­phen­yl)-2-[(2-phenyl­cyclo­hex-2-en-1-yl)imino]-1,3-thia­zol­idin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393268/
https://www.ncbi.nlm.nih.gov/pubmed/22807825
http://dx.doi.org/10.1107/S1600536812024646
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