2-sec-Butyl-1-(2-hy­droxy­eth­yl)-1H-benzimidazole-5-carboxylic acid

In the title compound, C(14)H(18)N(2)O(3), the carb­oxy­lic group is tilted by 12.00 (4)° with respect to the mean plane throught the benzimidazole ring system. The alcohol and carboxyl hydroxy groups are involved in intermolecular O—H⋯O and O—H⋯N hydrogen bonds, forming a two-dimensional network ex...

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Autores principales: Hamzah, Nurasyikin, Ngah, Nurziana, Abd Hamid, Shafida, Abdul Rahim, Aisyah Saad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393269/
https://www.ncbi.nlm.nih.gov/pubmed/22807826
http://dx.doi.org/10.1107/S1600536812023884
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author Hamzah, Nurasyikin
Ngah, Nurziana
Abd Hamid, Shafida
Abdul Rahim, Aisyah Saad
author_facet Hamzah, Nurasyikin
Ngah, Nurziana
Abd Hamid, Shafida
Abdul Rahim, Aisyah Saad
author_sort Hamzah, Nurasyikin
collection PubMed
description In the title compound, C(14)H(18)N(2)O(3), the carb­oxy­lic group is tilted by 12.00 (4)° with respect to the mean plane throught the benzimidazole ring system. The alcohol and carboxyl hydroxy groups are involved in intermolecular O—H⋯O and O—H⋯N hydrogen bonds, forming a two-dimensional network extending parallel the ab plane. The network is further stabilized by weak C—H⋯O inter­actions. The sec-butyl group is disordered over two sets of sites with refined occupancies of 0.484 (4) and 0.516 (4).
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spelling pubmed-33932692012-07-17 2-sec-Butyl-1-(2-hy­droxy­eth­yl)-1H-benzimidazole-5-carboxylic acid Hamzah, Nurasyikin Ngah, Nurziana Abd Hamid, Shafida Abdul Rahim, Aisyah Saad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(18)N(2)O(3), the carb­oxy­lic group is tilted by 12.00 (4)° with respect to the mean plane throught the benzimidazole ring system. The alcohol and carboxyl hydroxy groups are involved in intermolecular O—H⋯O and O—H⋯N hydrogen bonds, forming a two-dimensional network extending parallel the ab plane. The network is further stabilized by weak C—H⋯O inter­actions. The sec-butyl group is disordered over two sets of sites with refined occupancies of 0.484 (4) and 0.516 (4). International Union of Crystallography 2012-06-02 /pmc/articles/PMC3393269/ /pubmed/22807826 http://dx.doi.org/10.1107/S1600536812023884 Text en © Hamzah et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hamzah, Nurasyikin
Ngah, Nurziana
Abd Hamid, Shafida
Abdul Rahim, Aisyah Saad
2-sec-Butyl-1-(2-hy­droxy­eth­yl)-1H-benzimidazole-5-carboxylic acid
title 2-sec-Butyl-1-(2-hy­droxy­eth­yl)-1H-benzimidazole-5-carboxylic acid
title_full 2-sec-Butyl-1-(2-hy­droxy­eth­yl)-1H-benzimidazole-5-carboxylic acid
title_fullStr 2-sec-Butyl-1-(2-hy­droxy­eth­yl)-1H-benzimidazole-5-carboxylic acid
title_full_unstemmed 2-sec-Butyl-1-(2-hy­droxy­eth­yl)-1H-benzimidazole-5-carboxylic acid
title_short 2-sec-Butyl-1-(2-hy­droxy­eth­yl)-1H-benzimidazole-5-carboxylic acid
title_sort 2-sec-butyl-1-(2-hy­droxy­eth­yl)-1h-benzimidazole-5-carboxylic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393269/
https://www.ncbi.nlm.nih.gov/pubmed/22807826
http://dx.doi.org/10.1107/S1600536812023884
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AT abdulrahimaisyahsaad 2secbutyl12hydroxyethyl1hbenzimidazole5carboxylicacid

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