Methyl 3-[4-(4-nitro­benz­yloxy)phen­yl]propano­ate

The title compound, C(17)H(17)NO(5), crystallizes with two mol­ecules (A and B) in the asymmetric unit. The conformational structures of the two mol­ecules show small but significant differences in the dihedral angles between the two aryl rings with values of 18.8 (1)° for mol­ecule A and 7.5 (1)° f...

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Detalles Bibliográficos
Autores principales: Servinis, Linden, Fox, Bronwyn L., Healy, Peter C., Henderson, Luke C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393271/
https://www.ncbi.nlm.nih.gov/pubmed/22807828
http://dx.doi.org/10.1107/S1600536812024701
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author Servinis, Linden
Fox, Bronwyn L.
Healy, Peter C.
Henderson, Luke C.
author_facet Servinis, Linden
Fox, Bronwyn L.
Healy, Peter C.
Henderson, Luke C.
author_sort Servinis, Linden
collection PubMed
description The title compound, C(17)H(17)NO(5), crystallizes with two mol­ecules (A and B) in the asymmetric unit. The conformational structures of the two mol­ecules show small but significant differences in the dihedral angles between the two aryl rings with values of 18.8 (1)° for mol­ecule A and 7.5 (1)° for mol­ecule B. In mol­ecule A, the propano­ate group is twisted out of the plane of the benzene group [C(ar)—C(ar)—C—C torsion angle = −44.9 (2)°], while for mol­ecule B, this group lies closer to the plane [C(ar)—C(ar)—C—C torsion angle = 8.6 (3)°]. C—H⋯O inter­actions characterize the crystal-packing inter­actions in this compound.
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spelling pubmed-33932712012-07-17 Methyl 3-[4-(4-nitro­benz­yloxy)phen­yl]propano­ate Servinis, Linden Fox, Bronwyn L. Healy, Peter C. Henderson, Luke C. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(17)NO(5), crystallizes with two mol­ecules (A and B) in the asymmetric unit. The conformational structures of the two mol­ecules show small but significant differences in the dihedral angles between the two aryl rings with values of 18.8 (1)° for mol­ecule A and 7.5 (1)° for mol­ecule B. In mol­ecule A, the propano­ate group is twisted out of the plane of the benzene group [C(ar)—C(ar)—C—C torsion angle = −44.9 (2)°], while for mol­ecule B, this group lies closer to the plane [C(ar)—C(ar)—C—C torsion angle = 8.6 (3)°]. C—H⋯O inter­actions characterize the crystal-packing inter­actions in this compound. International Union of Crystallography 2012-06-02 /pmc/articles/PMC3393271/ /pubmed/22807828 http://dx.doi.org/10.1107/S1600536812024701 Text en © Servinis et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Servinis, Linden
Fox, Bronwyn L.
Healy, Peter C.
Henderson, Luke C.
Methyl 3-[4-(4-nitro­benz­yloxy)phen­yl]propano­ate
title Methyl 3-[4-(4-nitro­benz­yloxy)phen­yl]propano­ate
title_full Methyl 3-[4-(4-nitro­benz­yloxy)phen­yl]propano­ate
title_fullStr Methyl 3-[4-(4-nitro­benz­yloxy)phen­yl]propano­ate
title_full_unstemmed Methyl 3-[4-(4-nitro­benz­yloxy)phen­yl]propano­ate
title_short Methyl 3-[4-(4-nitro­benz­yloxy)phen­yl]propano­ate
title_sort methyl 3-[4-(4-nitro­benz­yloxy)phen­yl]propano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393271/
https://www.ncbi.nlm.nih.gov/pubmed/22807828
http://dx.doi.org/10.1107/S1600536812024701
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