Cargando…

(Z)-3-(4-Chloro­phen­yl)-2-(2-phenyl­cyclo­hex-2-en-1-yl­imino)­thia­zolidin-4-one

The title compound, C(21)H(19)ClN(2)OS, exists in a cis conformation with respect to the N=C bond [1.2608 (13) Å]. The cyclo­hexene ring adopts a distorted half-chair conformation. The thia­zolidine ring is close to being planar (r.m.s. deviation = 0.057 Å) and makes dihedral angles of 62.92 (6) and...

Descripción completa

Detalles Bibliográficos
Autores principales: Ooi, Chin Wei, Fun, Hoong-Kun, Quah, Ching Kheng, Sathishkumar, Murugan, Ponnuswamy, Alagusundaram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393272/
https://www.ncbi.nlm.nih.gov/pubmed/22807829
http://dx.doi.org/10.1107/S1600536812024294
Descripción
Sumario:The title compound, C(21)H(19)ClN(2)OS, exists in a cis conformation with respect to the N=C bond [1.2608 (13) Å]. The cyclo­hexene ring adopts a distorted half-chair conformation. The thia­zolidine ring is close to being planar (r.m.s. deviation = 0.057 Å) and makes dihedral angles of 62.92 (6) and 56.32 (6)°, respectively, with the benzene ring and the chloro-substituted benzene ring. The dihedral angle between the benzene ring and the chloro-substituted benzene ring is 72.91 (6)°. In the crystal, mol­ecules are linked by C—H⋯O and C—H⋯N hydrogen bonds into undulating sheets lying parallel to the bc plane. The crystal is further consolidated by C—H⋯π inter­actions.