2-(2,4-Difluoro­phen­yl)-5-nitro­pyridine

In the title mol­ecule, C(11)H(6)F(2)N(2)O(2), the benzene and pyridine rings form a dihedral angle of 32.57 (6)°. The nitro group is tilted with respect to the pyridine ring by 12.26 (9)°. An intra­molecular C—H⋯F hydrogen bond is present. In the crystal, mol­ecules inter­act through π–π stacking i...

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Detalles Bibliográficos
Autores principales: Sun, Feng, Shen, Xuan, Zhao, Rui, Wang, Xin, Zhu, Dun-Ru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393273/
https://www.ncbi.nlm.nih.gov/pubmed/22807830
http://dx.doi.org/10.1107/S1600536812024713
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author Sun, Feng
Shen, Xuan
Zhao, Rui
Wang, Xin
Zhu, Dun-Ru
author_facet Sun, Feng
Shen, Xuan
Zhao, Rui
Wang, Xin
Zhu, Dun-Ru
author_sort Sun, Feng
collection PubMed
description In the title mol­ecule, C(11)H(6)F(2)N(2)O(2), the benzene and pyridine rings form a dihedral angle of 32.57 (6)°. The nitro group is tilted with respect to the pyridine ring by 12.26 (9)°. An intra­molecular C—H⋯F hydrogen bond is present. In the crystal, mol­ecules inter­act through π–π stacking inter­actions [centroid–centroid distances = 3.7457 (14) Å], forming columnar arrangements along the b axis. The crystal packing is further enforced by inter­molecular C—H⋯O and C—H⋯N hydrogen bonds.
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spelling pubmed-33932732012-07-17 2-(2,4-Difluoro­phen­yl)-5-nitro­pyridine Sun, Feng Shen, Xuan Zhao, Rui Wang, Xin Zhu, Dun-Ru Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(11)H(6)F(2)N(2)O(2), the benzene and pyridine rings form a dihedral angle of 32.57 (6)°. The nitro group is tilted with respect to the pyridine ring by 12.26 (9)°. An intra­molecular C—H⋯F hydrogen bond is present. In the crystal, mol­ecules inter­act through π–π stacking inter­actions [centroid–centroid distances = 3.7457 (14) Å], forming columnar arrangements along the b axis. The crystal packing is further enforced by inter­molecular C—H⋯O and C—H⋯N hydrogen bonds. International Union of Crystallography 2012-06-02 /pmc/articles/PMC3393273/ /pubmed/22807830 http://dx.doi.org/10.1107/S1600536812024713 Text en © Sun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sun, Feng
Shen, Xuan
Zhao, Rui
Wang, Xin
Zhu, Dun-Ru
2-(2,4-Difluoro­phen­yl)-5-nitro­pyridine
title 2-(2,4-Difluoro­phen­yl)-5-nitro­pyridine
title_full 2-(2,4-Difluoro­phen­yl)-5-nitro­pyridine
title_fullStr 2-(2,4-Difluoro­phen­yl)-5-nitro­pyridine
title_full_unstemmed 2-(2,4-Difluoro­phen­yl)-5-nitro­pyridine
title_short 2-(2,4-Difluoro­phen­yl)-5-nitro­pyridine
title_sort 2-(2,4-difluoro­phen­yl)-5-nitro­pyridine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393273/
https://www.ncbi.nlm.nih.gov/pubmed/22807830
http://dx.doi.org/10.1107/S1600536812024713
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AT zhudunru 224difluorophenyl5nitropyridine

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