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11-[(E)-Benzyl­idene]-14-hy­droxy-8-phenyl-6-thia-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15(23),16,18,20-pentaen-10-one

In the title compound, C(34)H(28)N(2)O(2)S, the piperidine ring adopts a chair conformation. One of the pyrrolidine rings adopts an envelope conformation with the methyl­ene C atom at the flap whereas the other pyrrolidine ring and the thia­zolidine ring adopt half-chair conformations. The mean plan...

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Detalles Bibliográficos
Autores principales: Kumar, Raju Suresh, Osman, Hasnah, Almansour, Abdulrahman I., Arshad, Suhana, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393284/
https://www.ncbi.nlm.nih.gov/pubmed/22807841
http://dx.doi.org/10.1107/S1600536812024270
Descripción
Sumario:In the title compound, C(34)H(28)N(2)O(2)S, the piperidine ring adopts a chair conformation. One of the pyrrolidine rings adopts an envelope conformation with the methyl­ene C atom at the flap whereas the other pyrrolidine ring and the thia­zolidine ring adopt half-chair conformations. The mean plane of the dihydro­acenaphthyl­ene ring system [maximum deviation = 0.067 (1) Å] makes dihedral angles of 28.31 (5) and 31.32 (6)° with the two terminal benzene rings. An intra­molecular O—H⋯N hydrogen bond forms an S(5) ring motif. In the crystal, mol­ecules are linked by C—H⋯O and C—H⋯S hydrogen bonds into layers lying parallel to the ac plane.