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11-[(E)-Benzylidene]-14-hydroxy-8-phenyl-6-thia-3,13-diazaheptacyclo[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetracosa-1(22),15(23),16,18,20-pentaen-10-one
In the title compound, C(34)H(28)N(2)O(2)S, the piperidine ring adopts a chair conformation. One of the pyrrolidine rings adopts an envelope conformation with the methylene C atom at the flap whereas the other pyrrolidine ring and the thiazolidine ring adopt half-chair conformations. The mean plan...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393284/ https://www.ncbi.nlm.nih.gov/pubmed/22807841 http://dx.doi.org/10.1107/S1600536812024270 |
| _version_ | 1782237713776246784 |
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| author | Kumar, Raju Suresh Osman, Hasnah Almansour, Abdulrahman I. Arshad, Suhana Razak, Ibrahim Abdul |
| author_facet | Kumar, Raju Suresh Osman, Hasnah Almansour, Abdulrahman I. Arshad, Suhana Razak, Ibrahim Abdul |
| author_sort | Kumar, Raju Suresh |
| collection | PubMed |
| description | In the title compound, C(34)H(28)N(2)O(2)S, the piperidine ring adopts a chair conformation. One of the pyrrolidine rings adopts an envelope conformation with the methylene C atom at the flap whereas the other pyrrolidine ring and the thiazolidine ring adopt half-chair conformations. The mean plane of the dihydroacenaphthylene ring system [maximum deviation = 0.067 (1) Å] makes dihedral angles of 28.31 (5) and 31.32 (6)° with the two terminal benzene rings. An intramolecular O—H⋯N hydrogen bond forms an S(5) ring motif. In the crystal, molecules are linked by C—H⋯O and C—H⋯S hydrogen bonds into layers lying parallel to the ac plane. |
| format | Online Article Text |
| id | pubmed-3393284 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33932842012-07-17 11-[(E)-Benzylidene]-14-hydroxy-8-phenyl-6-thia-3,13-diazaheptacyclo[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetracosa-1(22),15(23),16,18,20-pentaen-10-one Kumar, Raju Suresh Osman, Hasnah Almansour, Abdulrahman I. Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(34)H(28)N(2)O(2)S, the piperidine ring adopts a chair conformation. One of the pyrrolidine rings adopts an envelope conformation with the methylene C atom at the flap whereas the other pyrrolidine ring and the thiazolidine ring adopt half-chair conformations. The mean plane of the dihydroacenaphthylene ring system [maximum deviation = 0.067 (1) Å] makes dihedral angles of 28.31 (5) and 31.32 (6)° with the two terminal benzene rings. An intramolecular O—H⋯N hydrogen bond forms an S(5) ring motif. In the crystal, molecules are linked by C—H⋯O and C—H⋯S hydrogen bonds into layers lying parallel to the ac plane. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393284/ /pubmed/22807841 http://dx.doi.org/10.1107/S1600536812024270 Text en © Kumar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Kumar, Raju Suresh Osman, Hasnah Almansour, Abdulrahman I. Arshad, Suhana Razak, Ibrahim Abdul 11-[(E)-Benzylidene]-14-hydroxy-8-phenyl-6-thia-3,13-diazaheptacyclo[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetracosa-1(22),15(23),16,18,20-pentaen-10-one |
| title | 11-[(E)-Benzylidene]-14-hydroxy-8-phenyl-6-thia-3,13-diazaheptacyclo[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetracosa-1(22),15(23),16,18,20-pentaen-10-one |
| title_full | 11-[(E)-Benzylidene]-14-hydroxy-8-phenyl-6-thia-3,13-diazaheptacyclo[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetracosa-1(22),15(23),16,18,20-pentaen-10-one |
| title_fullStr | 11-[(E)-Benzylidene]-14-hydroxy-8-phenyl-6-thia-3,13-diazaheptacyclo[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetracosa-1(22),15(23),16,18,20-pentaen-10-one |
| title_full_unstemmed | 11-[(E)-Benzylidene]-14-hydroxy-8-phenyl-6-thia-3,13-diazaheptacyclo[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetracosa-1(22),15(23),16,18,20-pentaen-10-one |
| title_short | 11-[(E)-Benzylidene]-14-hydroxy-8-phenyl-6-thia-3,13-diazaheptacyclo[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetracosa-1(22),15(23),16,18,20-pentaen-10-one |
| title_sort | 11-[(e)-benzylidene]-14-hydroxy-8-phenyl-6-thia-3,13-diazaheptacyclo[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetracosa-1(22),15(23),16,18,20-pentaen-10-one |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393284/ https://www.ncbi.nlm.nih.gov/pubmed/22807841 http://dx.doi.org/10.1107/S1600536812024270 |
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