rac-2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphth­yl: a racemic diphosphine ligand

The asymmetric unit of the title compound, C(44)H(32)P(2), conventionally abbreviated BINAP, is one half of the complete chiral BINAP mol­ecule, which adopts a C2 crystallographic point-group symmetry with a twofold axis splitting the mol­ecule in two identical halves; a center of symmetry between m...

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Detalles Bibliográficos
Autores principales: Niu, Feng, Chai, Wenxiang, Song, Li, Zhou, Mengbo, Liang, Jiaping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393302/
https://www.ncbi.nlm.nih.gov/pubmed/22807859
http://dx.doi.org/10.1107/S1600536812025603
Descripción
Sumario:The asymmetric unit of the title compound, C(44)H(32)P(2), conventionally abbreviated BINAP, is one half of the complete chiral BINAP mol­ecule, which adopts a C2 crystallographic point-group symmetry with a twofold axis splitting the mol­ecule in two identical halves; a center of symmetry between mol­ecules further determines the racemic pairs. There are no obvious supra­molecular inter­actions between adjacent BINAP mol­ecules.

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