rac-2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphth­yl: a racemic diphosphine ligand

The asymmetric unit of the title compound, C(44)H(32)P(2), conventionally abbreviated BINAP, is one half of the complete chiral BINAP mol­ecule, which adopts a C2 crystallographic point-group symmetry with a twofold axis splitting the mol­ecule in two identical halves; a center of symmetry between m...

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Detalles Bibliográficos
Autores principales: Niu, Feng, Chai, Wenxiang, Song, Li, Zhou, Mengbo, Liang, Jiaping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393302/
https://www.ncbi.nlm.nih.gov/pubmed/22807859
http://dx.doi.org/10.1107/S1600536812025603
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author Niu, Feng
Chai, Wenxiang
Song, Li
Zhou, Mengbo
Liang, Jiaping
author_facet Niu, Feng
Chai, Wenxiang
Song, Li
Zhou, Mengbo
Liang, Jiaping
author_sort Niu, Feng
collection PubMed
description The asymmetric unit of the title compound, C(44)H(32)P(2), conventionally abbreviated BINAP, is one half of the complete chiral BINAP mol­ecule, which adopts a C2 crystallographic point-group symmetry with a twofold axis splitting the mol­ecule in two identical halves; a center of symmetry between mol­ecules further determines the racemic pairs. There are no obvious supra­molecular inter­actions between adjacent BINAP mol­ecules.
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spelling pubmed-33933022012-07-17 rac-2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphth­yl: a racemic diphosphine ligand Niu, Feng Chai, Wenxiang Song, Li Zhou, Mengbo Liang, Jiaping Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(44)H(32)P(2), conventionally abbreviated BINAP, is one half of the complete chiral BINAP mol­ecule, which adopts a C2 crystallographic point-group symmetry with a twofold axis splitting the mol­ecule in two identical halves; a center of symmetry between mol­ecules further determines the racemic pairs. There are no obvious supra­molecular inter­actions between adjacent BINAP mol­ecules. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393302/ /pubmed/22807859 http://dx.doi.org/10.1107/S1600536812025603 Text en © Niu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Niu, Feng
Chai, Wenxiang
Song, Li
Zhou, Mengbo
Liang, Jiaping
rac-2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphth­yl: a racemic diphosphine ligand
title rac-2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphth­yl: a racemic diphosphine ligand
title_full rac-2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphth­yl: a racemic diphosphine ligand
title_fullStr rac-2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphth­yl: a racemic diphosphine ligand
title_full_unstemmed rac-2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphth­yl: a racemic diphosphine ligand
title_short rac-2,2′-Bis(diphenyl­phosphan­yl)-1,1′-binaphth­yl: a racemic diphosphine ligand
title_sort rac-2,2′-bis(diphenyl­phosphan­yl)-1,1′-binaphth­yl: a racemic diphosphine ligand
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393302/
https://www.ncbi.nlm.nih.gov/pubmed/22807859
http://dx.doi.org/10.1107/S1600536812025603
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