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4-(2-Benzoylbenzoyl)-N,N-diphenylaniline
The asymmetric unit of the title compound, C(32)H(23)NO(2), comprises two crystallographically independent molecules. In both molecules, the geometries about the N atoms deviate significantly from the ideal trigonal–planar geometry with bond-angle sums about the N atom of 359.32° in one molecule...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393304/ https://www.ncbi.nlm.nih.gov/pubmed/22807861 http://dx.doi.org/10.1107/S160053681202466X |
Sumario: | The asymmetric unit of the title compound, C(32)H(23)NO(2), comprises two crystallographically independent molecules. In both molecules, the geometries about the N atoms deviate significantly from the ideal trigonal–planar geometry with bond-angle sums about the N atom of 359.32° in one molecule and 359.86° in the other. The O atoms of the carbonyl groups are deviated significantly from the central benzene rings by 0.6747 (14) and −1.1223 (13) Å in one molecule and −0.6230 (13) and 1.1559 (12) Å in the other. In the diphenylaniline units, the terminal phenyl rings are almost orthogonal to each other, with dihedral angles of 89.79 (9) and 89.76 (9)°. The crystal structure features C—H⋯O and C—H⋯π interactions. |
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