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4-(2-Benzoylbenzoyl)-N,N-diphenylaniline
The asymmetric unit of the title compound, C(32)H(23)NO(2), comprises two crystallographically independent molecules. In both molecules, the geometries about the N atoms deviate significantly from the ideal trigonal–planar geometry with bond-angle sums about the N atom of 359.32° in one molecule...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393304/ https://www.ncbi.nlm.nih.gov/pubmed/22807861 http://dx.doi.org/10.1107/S160053681202466X |
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author | Narayanan, P. Sethusankar, K. Nandakumar, M. Mohanakrishnan, A. K. |
author_facet | Narayanan, P. Sethusankar, K. Nandakumar, M. Mohanakrishnan, A. K. |
author_sort | Narayanan, P. |
collection | PubMed |
description | The asymmetric unit of the title compound, C(32)H(23)NO(2), comprises two crystallographically independent molecules. In both molecules, the geometries about the N atoms deviate significantly from the ideal trigonal–planar geometry with bond-angle sums about the N atom of 359.32° in one molecule and 359.86° in the other. The O atoms of the carbonyl groups are deviated significantly from the central benzene rings by 0.6747 (14) and −1.1223 (13) Å in one molecule and −0.6230 (13) and 1.1559 (12) Å in the other. In the diphenylaniline units, the terminal phenyl rings are almost orthogonal to each other, with dihedral angles of 89.79 (9) and 89.76 (9)°. The crystal structure features C—H⋯O and C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3393304 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33933042012-07-17 4-(2-Benzoylbenzoyl)-N,N-diphenylaniline Narayanan, P. Sethusankar, K. Nandakumar, M. Mohanakrishnan, A. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(32)H(23)NO(2), comprises two crystallographically independent molecules. In both molecules, the geometries about the N atoms deviate significantly from the ideal trigonal–planar geometry with bond-angle sums about the N atom of 359.32° in one molecule and 359.86° in the other. The O atoms of the carbonyl groups are deviated significantly from the central benzene rings by 0.6747 (14) and −1.1223 (13) Å in one molecule and −0.6230 (13) and 1.1559 (12) Å in the other. In the diphenylaniline units, the terminal phenyl rings are almost orthogonal to each other, with dihedral angles of 89.79 (9) and 89.76 (9)°. The crystal structure features C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393304/ /pubmed/22807861 http://dx.doi.org/10.1107/S160053681202466X Text en © Narayanan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Narayanan, P. Sethusankar, K. Nandakumar, M. Mohanakrishnan, A. K. 4-(2-Benzoylbenzoyl)-N,N-diphenylaniline |
title | 4-(2-Benzoylbenzoyl)-N,N-diphenylaniline |
title_full | 4-(2-Benzoylbenzoyl)-N,N-diphenylaniline |
title_fullStr | 4-(2-Benzoylbenzoyl)-N,N-diphenylaniline |
title_full_unstemmed | 4-(2-Benzoylbenzoyl)-N,N-diphenylaniline |
title_short | 4-(2-Benzoylbenzoyl)-N,N-diphenylaniline |
title_sort | 4-(2-benzoylbenzoyl)-n,n-diphenylaniline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393304/ https://www.ncbi.nlm.nih.gov/pubmed/22807861 http://dx.doi.org/10.1107/S160053681202466X |
work_keys_str_mv | AT narayananp 42benzoylbenzoylnndiphenylaniline AT sethusankark 42benzoylbenzoylnndiphenylaniline AT nandakumarm 42benzoylbenzoylnndiphenylaniline AT mohanakrishnanak 42benzoylbenzoylnndiphenylaniline |