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4-(2-Benzoyl­benzoyl)-N,N-diphenyl­aniline

The asymmetric unit of the title compound, C(32)H(23)NO(2), comprises two crystallographically independent mol­ecules. In both mol­ecules, the geometries about the N atoms deviate significantly from the ideal trigonal–planar geometry with bond-angle sums about the N atom of 359.32° in one mol­ecule...

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Autores principales: Narayanan, P., Sethusankar, K., Nandakumar, M., Mohanakrishnan, A. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393304/
https://www.ncbi.nlm.nih.gov/pubmed/22807861
http://dx.doi.org/10.1107/S160053681202466X
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author Narayanan, P.
Sethusankar, K.
Nandakumar, M.
Mohanakrishnan, A. K.
author_facet Narayanan, P.
Sethusankar, K.
Nandakumar, M.
Mohanakrishnan, A. K.
author_sort Narayanan, P.
collection PubMed
description The asymmetric unit of the title compound, C(32)H(23)NO(2), comprises two crystallographically independent mol­ecules. In both mol­ecules, the geometries about the N atoms deviate significantly from the ideal trigonal–planar geometry with bond-angle sums about the N atom of 359.32° in one mol­ecule and 359.86° in the other. The O atoms of the carbonyl groups are deviated significantly from the central benzene rings by 0.6747 (14) and −1.1223 (13) Å in one molecule and −0.6230 (13) and 1.1559 (12) Å in the other. In the diphenyl­aniline units, the terminal phenyl rings are almost orthogonal to each other, with dihedral angles of 89.79 (9) and 89.76 (9)°. The crystal structure features C—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-33933042012-07-17 4-(2-Benzoyl­benzoyl)-N,N-diphenyl­aniline Narayanan, P. Sethusankar, K. Nandakumar, M. Mohanakrishnan, A. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(32)H(23)NO(2), comprises two crystallographically independent mol­ecules. In both mol­ecules, the geometries about the N atoms deviate significantly from the ideal trigonal–planar geometry with bond-angle sums about the N atom of 359.32° in one mol­ecule and 359.86° in the other. The O atoms of the carbonyl groups are deviated significantly from the central benzene rings by 0.6747 (14) and −1.1223 (13) Å in one molecule and −0.6230 (13) and 1.1559 (12) Å in the other. In the diphenyl­aniline units, the terminal phenyl rings are almost orthogonal to each other, with dihedral angles of 89.79 (9) and 89.76 (9)°. The crystal structure features C—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393304/ /pubmed/22807861 http://dx.doi.org/10.1107/S160053681202466X Text en © Narayanan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Narayanan, P.
Sethusankar, K.
Nandakumar, M.
Mohanakrishnan, A. K.
4-(2-Benzoyl­benzoyl)-N,N-diphenyl­aniline
title 4-(2-Benzoyl­benzoyl)-N,N-diphenyl­aniline
title_full 4-(2-Benzoyl­benzoyl)-N,N-diphenyl­aniline
title_fullStr 4-(2-Benzoyl­benzoyl)-N,N-diphenyl­aniline
title_full_unstemmed 4-(2-Benzoyl­benzoyl)-N,N-diphenyl­aniline
title_short 4-(2-Benzoyl­benzoyl)-N,N-diphenyl­aniline
title_sort 4-(2-benzoyl­benzoyl)-n,n-diphenyl­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393304/
https://www.ncbi.nlm.nih.gov/pubmed/22807861
http://dx.doi.org/10.1107/S160053681202466X
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