Dicyclo­hexyl­ammonium (S)-2-azido-3-phenyl­propano­ate

The asymmetric unit of the title compound, C(12)H(24)N(+)·C(9)H(8)N(3)O(2) (−), consists of two dicyclo­hexyl­ammonium cations linked to two (S)-2-azido-3-phenyl­propano­ate anions by four short N—H⋯O hydrogen bonds with N⋯O distances in the range 2.712 (3)–2.765 (3) Å. The dicyclo­hexyl­ammonium ca...

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Detalles Bibliográficos
Autores principales: Petrik, Sebastian J., Brown, Christopher L., Boyd, Sue E., Healy, Peter C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393318/
https://www.ncbi.nlm.nih.gov/pubmed/22807875
http://dx.doi.org/10.1107/S1600536812025536
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author Petrik, Sebastian J.
Brown, Christopher L.
Boyd, Sue E.
Healy, Peter C.
author_facet Petrik, Sebastian J.
Brown, Christopher L.
Boyd, Sue E.
Healy, Peter C.
author_sort Petrik, Sebastian J.
collection PubMed
description The asymmetric unit of the title compound, C(12)H(24)N(+)·C(9)H(8)N(3)O(2) (−), consists of two dicyclo­hexyl­ammonium cations linked to two (S)-2-azido-3-phenyl­propano­ate anions by four short N—H⋯O hydrogen bonds with N⋯O distances in the range 2.712 (3)–2.765 (3) Å. The dicyclo­hexyl­ammonium cations and the aryl and carboxyl­ate groups of the anion are related by a pseudo-inversion centre, with overall crystallographic inversion symmetry for the structure broken by the chirality of the α-C atoms of the anions.
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spelling pubmed-33933182012-07-17 Dicyclo­hexyl­ammonium (S)-2-azido-3-phenyl­propano­ate Petrik, Sebastian J. Brown, Christopher L. Boyd, Sue E. Healy, Peter C. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(12)H(24)N(+)·C(9)H(8)N(3)O(2) (−), consists of two dicyclo­hexyl­ammonium cations linked to two (S)-2-azido-3-phenyl­propano­ate anions by four short N—H⋯O hydrogen bonds with N⋯O distances in the range 2.712 (3)–2.765 (3) Å. The dicyclo­hexyl­ammonium cations and the aryl and carboxyl­ate groups of the anion are related by a pseudo-inversion centre, with overall crystallographic inversion symmetry for the structure broken by the chirality of the α-C atoms of the anions. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393318/ /pubmed/22807875 http://dx.doi.org/10.1107/S1600536812025536 Text en © Petrik et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Petrik, Sebastian J.
Brown, Christopher L.
Boyd, Sue E.
Healy, Peter C.
Dicyclo­hexyl­ammonium (S)-2-azido-3-phenyl­propano­ate
title Dicyclo­hexyl­ammonium (S)-2-azido-3-phenyl­propano­ate
title_full Dicyclo­hexyl­ammonium (S)-2-azido-3-phenyl­propano­ate
title_fullStr Dicyclo­hexyl­ammonium (S)-2-azido-3-phenyl­propano­ate
title_full_unstemmed Dicyclo­hexyl­ammonium (S)-2-azido-3-phenyl­propano­ate
title_short Dicyclo­hexyl­ammonium (S)-2-azido-3-phenyl­propano­ate
title_sort dicyclo­hexyl­ammonium (s)-2-azido-3-phenyl­propano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393318/
https://www.ncbi.nlm.nih.gov/pubmed/22807875
http://dx.doi.org/10.1107/S1600536812025536
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AT boydsuee dicyclohexylammoniums2azido3phenylpropanoate
AT healypeterc dicyclohexylammoniums2azido3phenylpropanoate

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