2,4-Dibromo-1,3-dimeth­oxy-5-methyl­benzene

The title compound, C(9)H(10)Br(2)O(2), crystallizes with two mol­ecules in the asymmetric unit. The two mol­ecules are essentially planar with slight differences in the (Br)C—C—O—C(H(3)) torsion angles [−176.7 (2) and −172.8 (2)° in one mol­ecule and 174.8 (2) and 179.9 (2)° in the other]. The crys...

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Detalles Bibliográficos
Autores principales: Pawar, Sunayna, Shaikh, Mahidansha, Koorbanally, Neil, Omondi, Bernard, Ramjugernath, Deresh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393326/
https://www.ncbi.nlm.nih.gov/pubmed/22807883
http://dx.doi.org/10.1107/S1600536812025767
Descripción
Sumario:The title compound, C(9)H(10)Br(2)O(2), crystallizes with two mol­ecules in the asymmetric unit. The two mol­ecules are essentially planar with slight differences in the (Br)C—C—O—C(H(3)) torsion angles [−176.7 (2) and −172.8 (2)° in one mol­ecule and 174.8 (2) and 179.9 (2)° in the other]. The crystal structure consists of sheets of mol­ecules linked through Br⋯Br [3.3547 (4), 3.3703 (4) and 3.5379 (4) Å] inter­actions, which are in turn connected through π–π inter­actions with centroid–centroid distances of 3.5902 (14) and 3.5956 (14) Å.

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