2-(1H-Benzimidazol-2-yl)-N-[(E)-(dimethyl­amino)­methyl­idene]benzene­sulfonamide

The asymmetric unit of the title compound, C(16)H(16)N(4)O(2)S, contains two mol­ecules (A and B) with similar conformations: the benzene rings are oriented at dihedral angles of 80.94 (10)° and 84.54 (10)° with their adjacent 1H-benzimidazole groups. In the crystal, the mol­ecules are connected by...

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Autores principales: Ashraf, Adnan, Tahir, M. Nawaz, Siddiqui, Waseeq Ahmad, Perveen, Nadia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393333/
https://www.ncbi.nlm.nih.gov/pubmed/22807890
http://dx.doi.org/10.1107/S1600536812025159
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author Ashraf, Adnan
Tahir, M. Nawaz
Siddiqui, Waseeq Ahmad
Perveen, Nadia
author_facet Ashraf, Adnan
Tahir, M. Nawaz
Siddiqui, Waseeq Ahmad
Perveen, Nadia
author_sort Ashraf, Adnan
collection PubMed
description The asymmetric unit of the title compound, C(16)H(16)N(4)O(2)S, contains two mol­ecules (A and B) with similar conformations: the benzene rings are oriented at dihedral angles of 80.94 (10)° and 84.54 (10)° with their adjacent 1H-benzimidazole groups. In the crystal, the mol­ecules are connected by N—H⋯N hydrogen bonds, forming separate C(4) chains of both the A and B mol­ecules along [010]. The A and B chains are cross-linked by several C—H⋯O inter­actions involving the benzene rings and the sulfonyl groups, which lead to R (2) (1)(5) loops in the linkage of the chains.
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spelling pubmed-33933332012-07-17 2-(1H-Benzimidazol-2-yl)-N-[(E)-(dimethyl­amino)­methyl­idene]benzene­sulfonamide Ashraf, Adnan Tahir, M. Nawaz Siddiqui, Waseeq Ahmad Perveen, Nadia Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(16)H(16)N(4)O(2)S, contains two mol­ecules (A and B) with similar conformations: the benzene rings are oriented at dihedral angles of 80.94 (10)° and 84.54 (10)° with their adjacent 1H-benzimidazole groups. In the crystal, the mol­ecules are connected by N—H⋯N hydrogen bonds, forming separate C(4) chains of both the A and B mol­ecules along [010]. The A and B chains are cross-linked by several C—H⋯O inter­actions involving the benzene rings and the sulfonyl groups, which lead to R (2) (1)(5) loops in the linkage of the chains. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393333/ /pubmed/22807890 http://dx.doi.org/10.1107/S1600536812025159 Text en © Ashraf et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ashraf, Adnan
Tahir, M. Nawaz
Siddiqui, Waseeq Ahmad
Perveen, Nadia
2-(1H-Benzimidazol-2-yl)-N-[(E)-(dimethyl­amino)­methyl­idene]benzene­sulfonamide
title 2-(1H-Benzimidazol-2-yl)-N-[(E)-(dimethyl­amino)­methyl­idene]benzene­sulfonamide
title_full 2-(1H-Benzimidazol-2-yl)-N-[(E)-(dimethyl­amino)­methyl­idene]benzene­sulfonamide
title_fullStr 2-(1H-Benzimidazol-2-yl)-N-[(E)-(dimethyl­amino)­methyl­idene]benzene­sulfonamide
title_full_unstemmed 2-(1H-Benzimidazol-2-yl)-N-[(E)-(dimethyl­amino)­methyl­idene]benzene­sulfonamide
title_short 2-(1H-Benzimidazol-2-yl)-N-[(E)-(dimethyl­amino)­methyl­idene]benzene­sulfonamide
title_sort 2-(1h-benzimidazol-2-yl)-n-[(e)-(dimethyl­amino)­methyl­idene]benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393333/
https://www.ncbi.nlm.nih.gov/pubmed/22807890
http://dx.doi.org/10.1107/S1600536812025159
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