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(2E)-2-(4-Hy­droxy-3-meth­oxy­benzyl­idene)hydrazinecarboxamide

In the title compound, C(9)H(11)N(3)O(3), two mol­ecules are present in the asymmetric unit in which the 4-hy­droxy-3-meth­oxy­benzaldehyde and hydrazinecarboxamide units are almost planar [with r.m.s. deviations 0.0212 and 0.0066 Å, respectively, in one mol­ecule and 0.0346 and 0.0095 Å, respective...

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Detalles Bibliográficos
Autores principales: Tahir, M. Nawaz, Ali, Akbar, Umar, M. Naveed, Hussain, Ishtiaq, Shad, Hazoor Ahmad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393335/
https://www.ncbi.nlm.nih.gov/pubmed/22807892
http://dx.doi.org/10.1107/S1600536812025299
Descripción
Sumario:In the title compound, C(9)H(11)N(3)O(3), two mol­ecules are present in the asymmetric unit in which the 4-hy­droxy-3-meth­oxy­benzaldehyde and hydrazinecarboxamide units are almost planar [with r.m.s. deviations 0.0212 and 0.0066 Å, respectively, in one mol­ecule and 0.0346 and 0.0095 Å, respectively, in the other] and are oriented at dihedral angles of 9.7 (3) and 16.6 (3)°. In both mol­ecules, two S(5) ring motifs are present due to N—H⋯N and O—H⋯O hydrogen bonds. In the crystal, the mol­ecules are dimerized with each other due to pairs of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. O—H⋯O hydrogen bonds lead to the formation of a three-dimensional network.