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(2E)-2-(4-Hy­droxy-3-meth­oxy­benzyl­idene)hydrazinecarboxamide

In the title compound, C(9)H(11)N(3)O(3), two mol­ecules are present in the asymmetric unit in which the 4-hy­droxy-3-meth­oxy­benzaldehyde and hydrazinecarboxamide units are almost planar [with r.m.s. deviations 0.0212 and 0.0066 Å, respectively, in one mol­ecule and 0.0346 and 0.0095 Å, respective...

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Autores principales: Tahir, M. Nawaz, Ali, Akbar, Umar, M. Naveed, Hussain, Ishtiaq, Shad, Hazoor Ahmad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393335/
https://www.ncbi.nlm.nih.gov/pubmed/22807892
http://dx.doi.org/10.1107/S1600536812025299
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author Tahir, M. Nawaz
Ali, Akbar
Umar, M. Naveed
Hussain, Ishtiaq
Shad, Hazoor Ahmad
author_facet Tahir, M. Nawaz
Ali, Akbar
Umar, M. Naveed
Hussain, Ishtiaq
Shad, Hazoor Ahmad
author_sort Tahir, M. Nawaz
collection PubMed
description In the title compound, C(9)H(11)N(3)O(3), two mol­ecules are present in the asymmetric unit in which the 4-hy­droxy-3-meth­oxy­benzaldehyde and hydrazinecarboxamide units are almost planar [with r.m.s. deviations 0.0212 and 0.0066 Å, respectively, in one mol­ecule and 0.0346 and 0.0095 Å, respectively, in the other] and are oriented at dihedral angles of 9.7 (3) and 16.6 (3)°. In both mol­ecules, two S(5) ring motifs are present due to N—H⋯N and O—H⋯O hydrogen bonds. In the crystal, the mol­ecules are dimerized with each other due to pairs of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. O—H⋯O hydrogen bonds lead to the formation of a three-dimensional network.
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spelling pubmed-33933352012-07-17 (2E)-2-(4-Hy­droxy-3-meth­oxy­benzyl­idene)hydrazinecarboxamide Tahir, M. Nawaz Ali, Akbar Umar, M. Naveed Hussain, Ishtiaq Shad, Hazoor Ahmad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(11)N(3)O(3), two mol­ecules are present in the asymmetric unit in which the 4-hy­droxy-3-meth­oxy­benzaldehyde and hydrazinecarboxamide units are almost planar [with r.m.s. deviations 0.0212 and 0.0066 Å, respectively, in one mol­ecule and 0.0346 and 0.0095 Å, respectively, in the other] and are oriented at dihedral angles of 9.7 (3) and 16.6 (3)°. In both mol­ecules, two S(5) ring motifs are present due to N—H⋯N and O—H⋯O hydrogen bonds. In the crystal, the mol­ecules are dimerized with each other due to pairs of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. O—H⋯O hydrogen bonds lead to the formation of a three-dimensional network. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393335/ /pubmed/22807892 http://dx.doi.org/10.1107/S1600536812025299 Text en © Tahir et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tahir, M. Nawaz
Ali, Akbar
Umar, M. Naveed
Hussain, Ishtiaq
Shad, Hazoor Ahmad
(2E)-2-(4-Hy­droxy-3-meth­oxy­benzyl­idene)hydrazinecarboxamide
title (2E)-2-(4-Hy­droxy-3-meth­oxy­benzyl­idene)hydrazinecarboxamide
title_full (2E)-2-(4-Hy­droxy-3-meth­oxy­benzyl­idene)hydrazinecarboxamide
title_fullStr (2E)-2-(4-Hy­droxy-3-meth­oxy­benzyl­idene)hydrazinecarboxamide
title_full_unstemmed (2E)-2-(4-Hy­droxy-3-meth­oxy­benzyl­idene)hydrazinecarboxamide
title_short (2E)-2-(4-Hy­droxy-3-meth­oxy­benzyl­idene)hydrazinecarboxamide
title_sort (2e)-2-(4-hy­droxy-3-meth­oxy­benzyl­idene)hydrazinecarboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393335/
https://www.ncbi.nlm.nih.gov/pubmed/22807892
http://dx.doi.org/10.1107/S1600536812025299
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