Cargando…

3-[(E)-(Pyridin-3-yl­imino)­meth­yl]phenol

Two independent mol­ecules are present in the asymmetric unit of the title compound, C(12)H(10)N(2)O, in which the 3-hy­droxy­benzaldehyde and the pyridin-3-amine units are almost planar [r.m.s. deviations of 0.0236 and 0.0116Å, respectively, in one mol­ecule and 0.0245 and 0.0162Å, respectively, in...

Descripción completa

Detalles Bibliográficos
Autores principales: Tahir, M. Nawaz, Ali, Akbar, Umar, M. Naveed, Hussain, Ishtiaq, Shad, Hazoor Ahmad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393889/
https://www.ncbi.nlm.nih.gov/pubmed/22798754
http://dx.doi.org/10.1107/S1600536812025822
Descripción
Sumario:Two independent mol­ecules are present in the asymmetric unit of the title compound, C(12)H(10)N(2)O, in which the 3-hy­droxy­benzaldehyde and the pyridin-3-amine units are almost planar [r.m.s. deviations of 0.0236 and 0.0116Å, respectively, in one mol­ecule and 0.0245 and 0.0162Å, respectively, in the other] and are oriented at dihedral angles of 7.21 (7) and 14.77 (7)°. In the crystal, mol­ecules of the same type form inversion dimers via pairs of O—H⋯N hydrogen bonds, forming R (2) (2)(20) ring motifs. There exist π–π inter­actions between the benzene and pyridine rings of molecules of the same type with centroid–centroid distances of 3.7127 (10) and 3.8439 (10) Å.