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3-[(E)-(Pyridin-3-ylimino)methyl]phenol
Two independent molecules are present in the asymmetric unit of the title compound, C(12)H(10)N(2)O, in which the 3-hydroxybenzaldehyde and the pyridin-3-amine units are almost planar [r.m.s. deviations of 0.0236 and 0.0116Å, respectively, in one molecule and 0.0245 and 0.0162Å, respectively, in...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393889/ https://www.ncbi.nlm.nih.gov/pubmed/22798754 http://dx.doi.org/10.1107/S1600536812025822 |
Sumario: | Two independent molecules are present in the asymmetric unit of the title compound, C(12)H(10)N(2)O, in which the 3-hydroxybenzaldehyde and the pyridin-3-amine units are almost planar [r.m.s. deviations of 0.0236 and 0.0116Å, respectively, in one molecule and 0.0245 and 0.0162Å, respectively, in the other] and are oriented at dihedral angles of 7.21 (7) and 14.77 (7)°. In the crystal, molecules of the same type form inversion dimers via pairs of O—H⋯N hydrogen bonds, forming R (2) (2)(20) ring motifs. There exist π–π interactions between the benzene and pyridine rings of molecules of the same type with centroid–centroid distances of 3.7127 (10) and 3.8439 (10) Å. |
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