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3-[(E)-(Pyridin-3-yl­imino)­meth­yl]phenol

Two independent mol­ecules are present in the asymmetric unit of the title compound, C(12)H(10)N(2)O, in which the 3-hy­droxy­benzaldehyde and the pyridin-3-amine units are almost planar [r.m.s. deviations of 0.0236 and 0.0116Å, respectively, in one mol­ecule and 0.0245 and 0.0162Å, respectively, in...

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Autores principales: Tahir, M. Nawaz, Ali, Akbar, Umar, M. Naveed, Hussain, Ishtiaq, Shad, Hazoor Ahmad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393889/
https://www.ncbi.nlm.nih.gov/pubmed/22798754
http://dx.doi.org/10.1107/S1600536812025822
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author Tahir, M. Nawaz
Ali, Akbar
Umar, M. Naveed
Hussain, Ishtiaq
Shad, Hazoor Ahmad
author_facet Tahir, M. Nawaz
Ali, Akbar
Umar, M. Naveed
Hussain, Ishtiaq
Shad, Hazoor Ahmad
author_sort Tahir, M. Nawaz
collection PubMed
description Two independent mol­ecules are present in the asymmetric unit of the title compound, C(12)H(10)N(2)O, in which the 3-hy­droxy­benzaldehyde and the pyridin-3-amine units are almost planar [r.m.s. deviations of 0.0236 and 0.0116Å, respectively, in one mol­ecule and 0.0245 and 0.0162Å, respectively, in the other] and are oriented at dihedral angles of 7.21 (7) and 14.77 (7)°. In the crystal, mol­ecules of the same type form inversion dimers via pairs of O—H⋯N hydrogen bonds, forming R (2) (2)(20) ring motifs. There exist π–π inter­actions between the benzene and pyridine rings of molecules of the same type with centroid–centroid distances of 3.7127 (10) and 3.8439 (10) Å.
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spelling pubmed-33938892012-07-13 3-[(E)-(Pyridin-3-yl­imino)­meth­yl]phenol Tahir, M. Nawaz Ali, Akbar Umar, M. Naveed Hussain, Ishtiaq Shad, Hazoor Ahmad Acta Crystallogr Sect E Struct Rep Online Organic Papers Two independent mol­ecules are present in the asymmetric unit of the title compound, C(12)H(10)N(2)O, in which the 3-hy­droxy­benzaldehyde and the pyridin-3-amine units are almost planar [r.m.s. deviations of 0.0236 and 0.0116Å, respectively, in one mol­ecule and 0.0245 and 0.0162Å, respectively, in the other] and are oriented at dihedral angles of 7.21 (7) and 14.77 (7)°. In the crystal, mol­ecules of the same type form inversion dimers via pairs of O—H⋯N hydrogen bonds, forming R (2) (2)(20) ring motifs. There exist π–π inter­actions between the benzene and pyridine rings of molecules of the same type with centroid–centroid distances of 3.7127 (10) and 3.8439 (10) Å. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393889/ /pubmed/22798754 http://dx.doi.org/10.1107/S1600536812025822 Text en © Tahir et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tahir, M. Nawaz
Ali, Akbar
Umar, M. Naveed
Hussain, Ishtiaq
Shad, Hazoor Ahmad
3-[(E)-(Pyridin-3-yl­imino)­meth­yl]phenol
title 3-[(E)-(Pyridin-3-yl­imino)­meth­yl]phenol
title_full 3-[(E)-(Pyridin-3-yl­imino)­meth­yl]phenol
title_fullStr 3-[(E)-(Pyridin-3-yl­imino)­meth­yl]phenol
title_full_unstemmed 3-[(E)-(Pyridin-3-yl­imino)­meth­yl]phenol
title_short 3-[(E)-(Pyridin-3-yl­imino)­meth­yl]phenol
title_sort 3-[(e)-(pyridin-3-yl­imino)­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393889/
https://www.ncbi.nlm.nih.gov/pubmed/22798754
http://dx.doi.org/10.1107/S1600536812025822
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