Cargando…
3-[(E)-(Pyridin-3-ylimino)methyl]phenol
Two independent molecules are present in the asymmetric unit of the title compound, C(12)H(10)N(2)O, in which the 3-hydroxybenzaldehyde and the pyridin-3-amine units are almost planar [r.m.s. deviations of 0.0236 and 0.0116Å, respectively, in one molecule and 0.0245 and 0.0162Å, respectively, in...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393889/ https://www.ncbi.nlm.nih.gov/pubmed/22798754 http://dx.doi.org/10.1107/S1600536812025822 |
_version_ | 1782237775042445312 |
---|---|
author | Tahir, M. Nawaz Ali, Akbar Umar, M. Naveed Hussain, Ishtiaq Shad, Hazoor Ahmad |
author_facet | Tahir, M. Nawaz Ali, Akbar Umar, M. Naveed Hussain, Ishtiaq Shad, Hazoor Ahmad |
author_sort | Tahir, M. Nawaz |
collection | PubMed |
description | Two independent molecules are present in the asymmetric unit of the title compound, C(12)H(10)N(2)O, in which the 3-hydroxybenzaldehyde and the pyridin-3-amine units are almost planar [r.m.s. deviations of 0.0236 and 0.0116Å, respectively, in one molecule and 0.0245 and 0.0162Å, respectively, in the other] and are oriented at dihedral angles of 7.21 (7) and 14.77 (7)°. In the crystal, molecules of the same type form inversion dimers via pairs of O—H⋯N hydrogen bonds, forming R (2) (2)(20) ring motifs. There exist π–π interactions between the benzene and pyridine rings of molecules of the same type with centroid–centroid distances of 3.7127 (10) and 3.8439 (10) Å. |
format | Online Article Text |
id | pubmed-3393889 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33938892012-07-13 3-[(E)-(Pyridin-3-ylimino)methyl]phenol Tahir, M. Nawaz Ali, Akbar Umar, M. Naveed Hussain, Ishtiaq Shad, Hazoor Ahmad Acta Crystallogr Sect E Struct Rep Online Organic Papers Two independent molecules are present in the asymmetric unit of the title compound, C(12)H(10)N(2)O, in which the 3-hydroxybenzaldehyde and the pyridin-3-amine units are almost planar [r.m.s. deviations of 0.0236 and 0.0116Å, respectively, in one molecule and 0.0245 and 0.0162Å, respectively, in the other] and are oriented at dihedral angles of 7.21 (7) and 14.77 (7)°. In the crystal, molecules of the same type form inversion dimers via pairs of O—H⋯N hydrogen bonds, forming R (2) (2)(20) ring motifs. There exist π–π interactions between the benzene and pyridine rings of molecules of the same type with centroid–centroid distances of 3.7127 (10) and 3.8439 (10) Å. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393889/ /pubmed/22798754 http://dx.doi.org/10.1107/S1600536812025822 Text en © Tahir et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tahir, M. Nawaz Ali, Akbar Umar, M. Naveed Hussain, Ishtiaq Shad, Hazoor Ahmad 3-[(E)-(Pyridin-3-ylimino)methyl]phenol |
title | 3-[(E)-(Pyridin-3-ylimino)methyl]phenol |
title_full | 3-[(E)-(Pyridin-3-ylimino)methyl]phenol |
title_fullStr | 3-[(E)-(Pyridin-3-ylimino)methyl]phenol |
title_full_unstemmed | 3-[(E)-(Pyridin-3-ylimino)methyl]phenol |
title_short | 3-[(E)-(Pyridin-3-ylimino)methyl]phenol |
title_sort | 3-[(e)-(pyridin-3-ylimino)methyl]phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393889/ https://www.ncbi.nlm.nih.gov/pubmed/22798754 http://dx.doi.org/10.1107/S1600536812025822 |
work_keys_str_mv | AT tahirmnawaz 3epyridin3yliminomethylphenol AT aliakbar 3epyridin3yliminomethylphenol AT umarmnaveed 3epyridin3yliminomethylphenol AT hussainishtiaq 3epyridin3yliminomethylphenol AT shadhazoorahmad 3epyridin3yliminomethylphenol |