(E)-4-Hy­droxy-2-{[(2-phenyl­eth­yl)iminium­yl]meth­yl}phenolate

The title Schiff base compound, C(15)H(15)NO(2), crystallized as the iminium–phenolate zwitterion. The H atom is localized on the imine N atom, forming a strong intra­molecular hydrogen bond with the phenolate O atom, and giving rise to an S(6) ring motif. The mol­ecule has an E conformation about t...

Descripción completa

Detalles Bibliográficos
Autores principales: Ortegon-Reyna, David, Garcias-Morales, Cesar, García-Báez, Efren V., Ariza-Castolo, Armando, Martínez-Martínez, Francisco J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393892/
https://www.ncbi.nlm.nih.gov/pubmed/22798757
http://dx.doi.org/10.1107/S1600536812025408
_version_ 1782237775714582528
author Ortegon-Reyna, David
Garcias-Morales, Cesar
García-Báez, Efren V.
Ariza-Castolo, Armando
Martínez-Martínez, Francisco J.
author_facet Ortegon-Reyna, David
Garcias-Morales, Cesar
García-Báez, Efren V.
Ariza-Castolo, Armando
Martínez-Martínez, Francisco J.
author_sort Ortegon-Reyna, David
collection PubMed
description The title Schiff base compound, C(15)H(15)NO(2), crystallized as the iminium–phenolate zwitterion. The H atom is localized on the imine N atom, forming a strong intra­molecular hydrogen bond with the phenolate O atom, and giving rise to an S(6) ring motif. The mol­ecule has an E conformation about the C=N bond. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, forming chains propagating along [010]. There are also C—H⋯O inter­actions present.
format Online
Article
Text
id pubmed-3393892
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33938922012-07-13 (E)-4-Hy­droxy-2-{[(2-phenyl­eth­yl)iminium­yl]meth­yl}phenolate Ortegon-Reyna, David Garcias-Morales, Cesar García-Báez, Efren V. Ariza-Castolo, Armando Martínez-Martínez, Francisco J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(15)H(15)NO(2), crystallized as the iminium–phenolate zwitterion. The H atom is localized on the imine N atom, forming a strong intra­molecular hydrogen bond with the phenolate O atom, and giving rise to an S(6) ring motif. The mol­ecule has an E conformation about the C=N bond. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, forming chains propagating along [010]. There are also C—H⋯O inter­actions present. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393892/ /pubmed/22798757 http://dx.doi.org/10.1107/S1600536812025408 Text en © Ortegon-Reyna et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ortegon-Reyna, David
Garcias-Morales, Cesar
García-Báez, Efren V.
Ariza-Castolo, Armando
Martínez-Martínez, Francisco J.
(E)-4-Hy­droxy-2-{[(2-phenyl­eth­yl)iminium­yl]meth­yl}phenolate
title (E)-4-Hy­droxy-2-{[(2-phenyl­eth­yl)iminium­yl]meth­yl}phenolate
title_full (E)-4-Hy­droxy-2-{[(2-phenyl­eth­yl)iminium­yl]meth­yl}phenolate
title_fullStr (E)-4-Hy­droxy-2-{[(2-phenyl­eth­yl)iminium­yl]meth­yl}phenolate
title_full_unstemmed (E)-4-Hy­droxy-2-{[(2-phenyl­eth­yl)iminium­yl]meth­yl}phenolate
title_short (E)-4-Hy­droxy-2-{[(2-phenyl­eth­yl)iminium­yl]meth­yl}phenolate
title_sort (e)-4-hy­droxy-2-{[(2-phenyl­eth­yl)iminium­yl]meth­yl}phenolate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393892/
https://www.ncbi.nlm.nih.gov/pubmed/22798757
http://dx.doi.org/10.1107/S1600536812025408
work_keys_str_mv AT ortegonreynadavid e4hydroxy22phenylethyliminiumylmethylphenolate
AT garciasmoralescesar e4hydroxy22phenylethyliminiumylmethylphenolate
AT garciabaezefrenv e4hydroxy22phenylethyliminiumylmethylphenolate
AT arizacastoloarmando e4hydroxy22phenylethyliminiumylmethylphenolate
AT martinezmartinezfranciscoj e4hydroxy22phenylethyliminiumylmethylphenolate

Ejemplares similares