3,3-Bis[(4-meth­oxy­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one

The piperidone ring in the title compound, C(20)H(23)NO(3)S(2), has a distorted half-chair conformation with the central methyl­ene atom of the propyl fragment lying 0.696 (1) Å out of the plane defined by the other five atoms (r.m.s. deviation = 0.071 Å). One of the S-bound phenyl rings is almost p...

Descripción completa

Detalles Bibliográficos
Autores principales: Caracelli, Ignez, Olivato, Paulo R., Cerqueira, Carlos R., Santos, Jean M. M., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393893/
https://www.ncbi.nlm.nih.gov/pubmed/22798758
http://dx.doi.org/10.1107/S1600536812025202
_version_ 1782237775940026368
author Caracelli, Ignez
Olivato, Paulo R.
Cerqueira, Carlos R.
Santos, Jean M. M.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Caracelli, Ignez
Olivato, Paulo R.
Cerqueira, Carlos R.
Santos, Jean M. M.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Caracelli, Ignez
collection PubMed
description The piperidone ring in the title compound, C(20)H(23)NO(3)S(2), has a distorted half-chair conformation with the central methyl­ene atom of the propyl fragment lying 0.696 (1) Å out of the plane defined by the other five atoms (r.m.s. deviation = 0.071 Å). One of the S-bound phenyl rings is almost perpendicular to the mean plane through the piperidone ring, whereas the other is splayed [dihedral angles = 71.95 (6) and 38.42 (6)°]. In the crystal, C—H⋯O and C—H⋯π inter­actions lead to the formation of supra­molecular layers in the ab plane.
format Online
Article
Text
id pubmed-3393893
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33938932012-07-13 3,3-Bis[(4-meth­oxy­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one Caracelli, Ignez Olivato, Paulo R. Cerqueira, Carlos R. Santos, Jean M. M. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The piperidone ring in the title compound, C(20)H(23)NO(3)S(2), has a distorted half-chair conformation with the central methyl­ene atom of the propyl fragment lying 0.696 (1) Å out of the plane defined by the other five atoms (r.m.s. deviation = 0.071 Å). One of the S-bound phenyl rings is almost perpendicular to the mean plane through the piperidone ring, whereas the other is splayed [dihedral angles = 71.95 (6) and 38.42 (6)°]. In the crystal, C—H⋯O and C—H⋯π inter­actions lead to the formation of supra­molecular layers in the ab plane. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393893/ /pubmed/22798758 http://dx.doi.org/10.1107/S1600536812025202 Text en © Caracelli et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Caracelli, Ignez
Olivato, Paulo R.
Cerqueira, Carlos R.
Santos, Jean M. M.
Ng, Seik Weng
Tiekink, Edward R. T.
3,3-Bis[(4-meth­oxy­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
title 3,3-Bis[(4-meth­oxy­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
title_full 3,3-Bis[(4-meth­oxy­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
title_fullStr 3,3-Bis[(4-meth­oxy­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
title_full_unstemmed 3,3-Bis[(4-meth­oxy­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
title_short 3,3-Bis[(4-meth­oxy­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
title_sort 3,3-bis[(4-meth­oxy­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393893/
https://www.ncbi.nlm.nih.gov/pubmed/22798758
http://dx.doi.org/10.1107/S1600536812025202
work_keys_str_mv AT caracelliignez 33bis4methoxyphenylsulfanyl1methylpiperidin2one
AT olivatopaulor 33bis4methoxyphenylsulfanyl1methylpiperidin2one
AT cerqueiracarlosr 33bis4methoxyphenylsulfanyl1methylpiperidin2one
AT santosjeanmm 33bis4methoxyphenylsulfanyl1methylpiperidin2one
AT ngseikweng 33bis4methoxyphenylsulfanyl1methylpiperidin2one
AT tiekinkedwardrt 33bis4methoxyphenylsulfanyl1methylpiperidin2one

Ejemplares similares