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(E,E)-1,2-Bis[3-(prop-2-yn-1-yloxy)benzylidene]hydrazine
The molecule of the title compound, C(20)H(16)N(2)O(2), is centrosymmetric, the inversion center being located at the mid-point of the central azine bond. The conformation around the C=N bond is E. The whole molecule (except for the H atoms) is essentially planar, with an r.m.s. deviation of 0.07 ...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393903/ https://www.ncbi.nlm.nih.gov/pubmed/22798768 http://dx.doi.org/10.1107/S1600536812025524 |
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author | Al-Mehana, Wisam Naji Atiyah Yahya, Rosiyah Sonsudin, Faridah Lo, Kong Mun |
author_facet | Al-Mehana, Wisam Naji Atiyah Yahya, Rosiyah Sonsudin, Faridah Lo, Kong Mun |
author_sort | Al-Mehana, Wisam Naji Atiyah |
collection | PubMed |
description | The molecule of the title compound, C(20)H(16)N(2)O(2), is centrosymmetric, the inversion center being located at the mid-point of the central azine bond. The conformation around the C=N bond is E. The whole molecule (except for the H atoms) is essentially planar, with an r.m.s. deviation of 0.07 Å. In the crystal, molecules are linked head-to-tail by pairs of C—H⋯O hydrogen bonds, forming inversion dimers, and resulting in the formation of chains propagating along [011]. |
format | Online Article Text |
id | pubmed-3393903 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33939032012-07-13 (E,E)-1,2-Bis[3-(prop-2-yn-1-yloxy)benzylidene]hydrazine Al-Mehana, Wisam Naji Atiyah Yahya, Rosiyah Sonsudin, Faridah Lo, Kong Mun Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(20)H(16)N(2)O(2), is centrosymmetric, the inversion center being located at the mid-point of the central azine bond. The conformation around the C=N bond is E. The whole molecule (except for the H atoms) is essentially planar, with an r.m.s. deviation of 0.07 Å. In the crystal, molecules are linked head-to-tail by pairs of C—H⋯O hydrogen bonds, forming inversion dimers, and resulting in the formation of chains propagating along [011]. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393903/ /pubmed/22798768 http://dx.doi.org/10.1107/S1600536812025524 Text en © Al-Mehana et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Al-Mehana, Wisam Naji Atiyah Yahya, Rosiyah Sonsudin, Faridah Lo, Kong Mun (E,E)-1,2-Bis[3-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
title | (E,E)-1,2-Bis[3-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
title_full | (E,E)-1,2-Bis[3-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
title_fullStr | (E,E)-1,2-Bis[3-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
title_full_unstemmed | (E,E)-1,2-Bis[3-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
title_short | (E,E)-1,2-Bis[3-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
title_sort | (e,e)-1,2-bis[3-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393903/ https://www.ncbi.nlm.nih.gov/pubmed/22798768 http://dx.doi.org/10.1107/S1600536812025524 |
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