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(3Z,3′E)-3,3′-[Cyclo­hexane-1,2-diylbis(aza­nylyl­idene)]bis­(indolin-2-one) N,N-dimethyl­formamide monosolvate dihydrate

In the Schiff base mol­ecule of the title compound, C(22)H(20)N(4)O(2)·C(3)H(7)NO·2H(2)O, the cyclo­hexane ring adopts a chair conformation with the two imine groups linked at the equatorial positions. The two indolin-2-one ring systems make a dihedral angle of 65.63 (5)°. In the crystal, the Schiff...

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Autores principales: Pezeshkpour, Shaghayegh, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393919/
https://www.ncbi.nlm.nih.gov/pubmed/22798784
http://dx.doi.org/10.1107/S1600536812026335
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author Pezeshkpour, Shaghayegh
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Pezeshkpour, Shaghayegh
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Pezeshkpour, Shaghayegh
collection PubMed
description In the Schiff base mol­ecule of the title compound, C(22)H(20)N(4)O(2)·C(3)H(7)NO·2H(2)O, the cyclo­hexane ring adopts a chair conformation with the two imine groups linked at the equatorial positions. The two indolin-2-one ring systems make a dihedral angle of 65.63 (5)°. In the crystal, the Schiff base mol­ecules are connected through bifurcated N—H⋯(O,N) hydrogen bonds, forming inversion dimers. The water molecules link the dimers and the dimethylformamide molecules via O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds. Together with C—H⋯π and π–π [centroid–centroid distance = 3.3889 (10) Å] inter­actions a three-dimensional supra­molecular structure is formed.
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spelling pubmed-33939192012-07-13 (3Z,3′E)-3,3′-[Cyclo­hexane-1,2-diylbis(aza­nylyl­idene)]bis­(indolin-2-one) N,N-dimethyl­formamide monosolvate dihydrate Pezeshkpour, Shaghayegh Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Organic Papers In the Schiff base mol­ecule of the title compound, C(22)H(20)N(4)O(2)·C(3)H(7)NO·2H(2)O, the cyclo­hexane ring adopts a chair conformation with the two imine groups linked at the equatorial positions. The two indolin-2-one ring systems make a dihedral angle of 65.63 (5)°. In the crystal, the Schiff base mol­ecules are connected through bifurcated N—H⋯(O,N) hydrogen bonds, forming inversion dimers. The water molecules link the dimers and the dimethylformamide molecules via O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds. Together with C—H⋯π and π–π [centroid–centroid distance = 3.3889 (10) Å] inter­actions a three-dimensional supra­molecular structure is formed. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393919/ /pubmed/22798784 http://dx.doi.org/10.1107/S1600536812026335 Text en © Pezeshkpour et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pezeshkpour, Shaghayegh
Khaledi, Hamid
Mohd Ali, Hapipah
(3Z,3′E)-3,3′-[Cyclo­hexane-1,2-diylbis(aza­nylyl­idene)]bis­(indolin-2-one) N,N-dimethyl­formamide monosolvate dihydrate
title (3Z,3′E)-3,3′-[Cyclo­hexane-1,2-diylbis(aza­nylyl­idene)]bis­(indolin-2-one) N,N-dimethyl­formamide monosolvate dihydrate
title_full (3Z,3′E)-3,3′-[Cyclo­hexane-1,2-diylbis(aza­nylyl­idene)]bis­(indolin-2-one) N,N-dimethyl­formamide monosolvate dihydrate
title_fullStr (3Z,3′E)-3,3′-[Cyclo­hexane-1,2-diylbis(aza­nylyl­idene)]bis­(indolin-2-one) N,N-dimethyl­formamide monosolvate dihydrate
title_full_unstemmed (3Z,3′E)-3,3′-[Cyclo­hexane-1,2-diylbis(aza­nylyl­idene)]bis­(indolin-2-one) N,N-dimethyl­formamide monosolvate dihydrate
title_short (3Z,3′E)-3,3′-[Cyclo­hexane-1,2-diylbis(aza­nylyl­idene)]bis­(indolin-2-one) N,N-dimethyl­formamide monosolvate dihydrate
title_sort (3z,3′e)-3,3′-[cyclo­hexane-1,2-diylbis(aza­nylyl­idene)]bis­(indolin-2-one) n,n-dimethyl­formamide monosolvate dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393919/
https://www.ncbi.nlm.nih.gov/pubmed/22798784
http://dx.doi.org/10.1107/S1600536812026335
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