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(3Z,3′E)-3,3′-[Cyclohexane-1,2-diylbis(azanylylidene)]bis(indolin-2-one) N,N-dimethylformamide monosolvate dihydrate
In the Schiff base molecule of the title compound, C(22)H(20)N(4)O(2)·C(3)H(7)NO·2H(2)O, the cyclohexane ring adopts a chair conformation with the two imine groups linked at the equatorial positions. The two indolin-2-one ring systems make a dihedral angle of 65.63 (5)°. In the crystal, the Schiff...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393919/ https://www.ncbi.nlm.nih.gov/pubmed/22798784 http://dx.doi.org/10.1107/S1600536812026335 |
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author | Pezeshkpour, Shaghayegh Khaledi, Hamid Mohd Ali, Hapipah |
author_facet | Pezeshkpour, Shaghayegh Khaledi, Hamid Mohd Ali, Hapipah |
author_sort | Pezeshkpour, Shaghayegh |
collection | PubMed |
description | In the Schiff base molecule of the title compound, C(22)H(20)N(4)O(2)·C(3)H(7)NO·2H(2)O, the cyclohexane ring adopts a chair conformation with the two imine groups linked at the equatorial positions. The two indolin-2-one ring systems make a dihedral angle of 65.63 (5)°. In the crystal, the Schiff base molecules are connected through bifurcated N—H⋯(O,N) hydrogen bonds, forming inversion dimers. The water molecules link the dimers and the dimethylformamide molecules via O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds. Together with C—H⋯π and π–π [centroid–centroid distance = 3.3889 (10) Å] interactions a three-dimensional supramolecular structure is formed. |
format | Online Article Text |
id | pubmed-3393919 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33939192012-07-13 (3Z,3′E)-3,3′-[Cyclohexane-1,2-diylbis(azanylylidene)]bis(indolin-2-one) N,N-dimethylformamide monosolvate dihydrate Pezeshkpour, Shaghayegh Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Organic Papers In the Schiff base molecule of the title compound, C(22)H(20)N(4)O(2)·C(3)H(7)NO·2H(2)O, the cyclohexane ring adopts a chair conformation with the two imine groups linked at the equatorial positions. The two indolin-2-one ring systems make a dihedral angle of 65.63 (5)°. In the crystal, the Schiff base molecules are connected through bifurcated N—H⋯(O,N) hydrogen bonds, forming inversion dimers. The water molecules link the dimers and the dimethylformamide molecules via O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds. Together with C—H⋯π and π–π [centroid–centroid distance = 3.3889 (10) Å] interactions a three-dimensional supramolecular structure is formed. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393919/ /pubmed/22798784 http://dx.doi.org/10.1107/S1600536812026335 Text en © Pezeshkpour et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Pezeshkpour, Shaghayegh Khaledi, Hamid Mohd Ali, Hapipah (3Z,3′E)-3,3′-[Cyclohexane-1,2-diylbis(azanylylidene)]bis(indolin-2-one) N,N-dimethylformamide monosolvate dihydrate |
title | (3Z,3′E)-3,3′-[Cyclohexane-1,2-diylbis(azanylylidene)]bis(indolin-2-one) N,N-dimethylformamide monosolvate dihydrate |
title_full | (3Z,3′E)-3,3′-[Cyclohexane-1,2-diylbis(azanylylidene)]bis(indolin-2-one) N,N-dimethylformamide monosolvate dihydrate |
title_fullStr | (3Z,3′E)-3,3′-[Cyclohexane-1,2-diylbis(azanylylidene)]bis(indolin-2-one) N,N-dimethylformamide monosolvate dihydrate |
title_full_unstemmed | (3Z,3′E)-3,3′-[Cyclohexane-1,2-diylbis(azanylylidene)]bis(indolin-2-one) N,N-dimethylformamide monosolvate dihydrate |
title_short | (3Z,3′E)-3,3′-[Cyclohexane-1,2-diylbis(azanylylidene)]bis(indolin-2-one) N,N-dimethylformamide monosolvate dihydrate |
title_sort | (3z,3′e)-3,3′-[cyclohexane-1,2-diylbis(azanylylidene)]bis(indolin-2-one) n,n-dimethylformamide monosolvate dihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393919/ https://www.ncbi.nlm.nih.gov/pubmed/22798784 http://dx.doi.org/10.1107/S1600536812026335 |
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