(E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-chloro­benzene­sulfonate

In the title compound, C(25)H(22)ClN(3)O(5)S, the two N atoms in the pyrazole ring have a pyramidal environment, with the sums of the valence angles around them being 349.3 (2) and 357.5 (2)°. The phenyl ring is twisted by 50.97 (12)° from the pyrazole mean plane. In the crystal, pairs of weak C—H⋯O...

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Autor principal: Lei, Tian-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393922/
https://www.ncbi.nlm.nih.gov/pubmed/22798787
http://dx.doi.org/10.1107/S160053681202627X
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author Lei, Tian-Xiang
author_facet Lei, Tian-Xiang
author_sort Lei, Tian-Xiang
collection PubMed
description In the title compound, C(25)H(22)ClN(3)O(5)S, the two N atoms in the pyrazole ring have a pyramidal environment, with the sums of the valence angles around them being 349.3 (2) and 357.5 (2)°. The phenyl ring is twisted by 50.97 (12)° from the pyrazole mean plane. In the crystal, pairs of weak C—H⋯O hydrogen bonds link the mol­ecules into inversion dimers.
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spelling pubmed-33939222012-07-13 (E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-chloro­benzene­sulfonate Lei, Tian-Xiang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(22)ClN(3)O(5)S, the two N atoms in the pyrazole ring have a pyramidal environment, with the sums of the valence angles around them being 349.3 (2) and 357.5 (2)°. The phenyl ring is twisted by 50.97 (12)° from the pyrazole mean plane. In the crystal, pairs of weak C—H⋯O hydrogen bonds link the mol­ecules into inversion dimers. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393922/ /pubmed/22798787 http://dx.doi.org/10.1107/S160053681202627X Text en © Tian-Xiang Lei 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lei, Tian-Xiang
(E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-chloro­benzene­sulfonate
title (E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-chloro­benzene­sulfonate
title_full (E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-chloro­benzene­sulfonate
title_fullStr (E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-chloro­benzene­sulfonate
title_full_unstemmed (E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-chloro­benzene­sulfonate
title_short (E)-5-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-chloro­benzene­sulfonate
title_sort (e)-5-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1h-pyrazol-4-yl)imino­meth­yl]-2-meth­oxy­phenyl 4-chloro­benzene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393922/
https://www.ncbi.nlm.nih.gov/pubmed/22798787
http://dx.doi.org/10.1107/S160053681202627X
work_keys_str_mv AT leitianxiang e515dimethyl3oxo2phenyl23dihydro1hpyrazol4yliminomethyl2methoxyphenyl4chlorobenzenesulfonate

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